100-K superconducting phases in the Tl-Ca-Ba-Cu-O system

R. M. Hazen; L. W. Finger; R. J. Angel; C. T. Prewitt; N. L. Ross; C. G. Hadidiacos; P. J. Heaney; D. R. Veblen; Z. Z. Sheng; A. El Ali; A. M. Hermann

doi:10.1103/PhysRevLett.60.1657

100-K superconducting phases in the Tl-Ca-Ba-Cu-O system

R. M. Hazen
, L. W. Finger
, R. J. Angel
, C. T. Prewitt
, N. L. Ross
, C. G. Hadidiacos
, P. J. Heaney
, D. R. Veblen
, Z. Z. Sheng
, A. El Ali
, A. M. Hermann

Research output: Contribution to journal › Article › peer-review

362 Scopus citations

Abstract

Two superconducting phases, Tl2Ca2Ba2Cu3O10 (2223) and Tl2Ca1Ba2Cu2)8 (2122), both with onset Tc near 120 K and zero resistivity at 100 K, have been isolated from samples in the Tl-Ca-Ba-Cu-O system. The new 2223 superconductor has a 5.40×5.40×36.253 pseudotetragonal unit cell. The 2122 superconductor, which appears to be structurally related to Bi2CaSr2Cu2O8, has a 5.44×5.44×29.553 pseudotetragonal subcell. The 2223 phase is probably related to 2122 by the addition of extra calcium and copper layers.

Original language	English (US)
Pages (from-to)	1657-1660
Number of pages	4
Journal	Physical review letters
Volume	60
Issue number	16
DOIs	https://doi.org/10.1103/PhysRevLett.60.1657
State	Published - 1988

All Science Journal Classification (ASJC) codes

General Physics and Astronomy

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10.1103/PhysRevLett.60.1657

Cite this

@article{34686cc82a48462098ba836936f55e59,

title = "100-K superconducting phases in the Tl-Ca-Ba-Cu-O system",

abstract = "Two superconducting phases, Tl2Ca2Ba2Cu3O10 (2223) and Tl2Ca1Ba2Cu2)8 (2122), both with onset Tc near 120 K and zero resistivity at 100 K, have been isolated from samples in the Tl-Ca-Ba-Cu-O system. The new 2223 superconductor has a 5.40×5.40×36.253 pseudotetragonal unit cell. The 2122 superconductor, which appears to be structurally related to Bi2CaSr2Cu2O8, has a 5.44×5.44×29.553 pseudotetragonal subcell. The 2223 phase is probably related to 2122 by the addition of extra calcium and copper layers.",

author = "Hazen, \{R. M.\} and Finger, \{L. W.\} and Angel, \{R. J.\} and Prewitt, \{C. T.\} and Ross, \{N. L.\} and Hadidiacos, \{C. G.\} and Heaney, \{P. J.\} and Veblen, \{D. R.\} and Sheng, \{Z. Z.\} and \{El Ali\}, A. and Hermann, \{A. M.\}",

year = "1988",

doi = "10.1103/PhysRevLett.60.1657",

language = "English (US)",

volume = "60",

pages = "1657--1660",

journal = "Physical review letters",

issn = "0031-9007",

publisher = "American Physical Society",

number = "16",

}

TY - JOUR

T1 - 100-K superconducting phases in the Tl-Ca-Ba-Cu-O system

AU - Hazen, R. M.

AU - Finger, L. W.

AU - Angel, R. J.

AU - Prewitt, C. T.

AU - Ross, N. L.

AU - Hadidiacos, C. G.

AU - Heaney, P. J.

AU - Veblen, D. R.

AU - Sheng, Z. Z.

AU - El Ali, A.

AU - Hermann, A. M.

PY - 1988

Y1 - 1988

N2 - Two superconducting phases, Tl2Ca2Ba2Cu3O10 (2223) and Tl2Ca1Ba2Cu2)8 (2122), both with onset Tc near 120 K and zero resistivity at 100 K, have been isolated from samples in the Tl-Ca-Ba-Cu-O system. The new 2223 superconductor has a 5.40×5.40×36.253 pseudotetragonal unit cell. The 2122 superconductor, which appears to be structurally related to Bi2CaSr2Cu2O8, has a 5.44×5.44×29.553 pseudotetragonal subcell. The 2223 phase is probably related to 2122 by the addition of extra calcium and copper layers.

AB - Two superconducting phases, Tl2Ca2Ba2Cu3O10 (2223) and Tl2Ca1Ba2Cu2)8 (2122), both with onset Tc near 120 K and zero resistivity at 100 K, have been isolated from samples in the Tl-Ca-Ba-Cu-O system. The new 2223 superconductor has a 5.40×5.40×36.253 pseudotetragonal unit cell. The 2122 superconductor, which appears to be structurally related to Bi2CaSr2Cu2O8, has a 5.44×5.44×29.553 pseudotetragonal subcell. The 2223 phase is probably related to 2122 by the addition of extra calcium and copper layers.

UR - https://www.scopus.com/pages/publications/35949008235

UR - https://www.scopus.com/pages/publications/35949008235#tab=citedBy

U2 - 10.1103/PhysRevLett.60.1657

DO - 10.1103/PhysRevLett.60.1657

M3 - Article

AN - SCOPUS:35949008235

SN - 0031-9007

VL - 60

SP - 1657

EP - 1660

JO - Physical review letters

JF - Physical review letters

IS - 16

ER -

100-K superconducting phases in the Tl-Ca-Ba-Cu-O system

Abstract

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