TY - JOUR
T1 - (2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato) iron(III)
AU - Xu, Nan
AU - Powell, Douglas R.
AU - Richter-Addo, George B.
PY - 2008
Y1 - 2008
N2 - The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) Å toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN4O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.
AB - The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) Å toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN4O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.
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U2 - 10.1107/S1600536808031504
DO - 10.1107/S1600536808031504
M3 - Article
C2 - 21580825
AN - SCOPUS:55749085843
SN - 1600-5368
VL - 64
SP - m1366
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 11
ER -