(2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato) iron(III)

Nan Xu; Douglas R. Powell; George B. Richter-Addo

doi:10.1107/S1600536808031504

(2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato) iron(III)

Nan Xu
, Douglas R. Powell
, George B. Richter-Addo

Division of Mathematics & Natural Sciences (Altoona)

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) Å toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN4O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.

Original language	English (US)
Pages (from-to)	m1366
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	11
DOIs	https://doi.org/10.1107/S1600536808031504
State	Published - 2008

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536808031504

Cite this

@article{11e1c62f2b584607b497493d2549502d,

title = "(2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato) iron(III)",

abstract = "The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) {\AA} toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN4O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.",

author = "Nan Xu and Powell, \{Douglas R.\} and Richter-Addo, \{George B.\}",

year = "2008",

doi = "10.1107/S1600536808031504",

language = "English (US)",

volume = "64",

pages = "m1366",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - (2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato) iron(III)

AU - Xu, Nan

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

PY - 2008

Y1 - 2008

N2 - The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) Å toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN4O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.

AB - The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) Å toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN4O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.

UR - https://www.scopus.com/pages/publications/55749085843

UR - https://www.scopus.com/pages/publications/55749085843#tab=citedBy

U2 - 10.1107/S1600536808031504

DO - 10.1107/S1600536808031504

M3 - Article

C2 - 21580825

AN - SCOPUS:55749085843

SN - 1600-5368

VL - 64

SP - m1366

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

(2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato) iron(III)

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this