A catalytically driven organometallic molecular motor

Ryan A. Pavlick; Krishna K. Dey; Andrew Sirjoosingh; Alan Benesi; Ayusman Sen

doi:10.1039/c2nr32518g

A catalytically driven organometallic molecular motor

Ryan A. Pavlick, Krishna K. Dey, Andrew Sirjoosingh, Alan Benesi, Ayusman Sen

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

We have observed by NMR spectroscopy that the diffusive movement of a ruthenium-based Grubbs' catalyst increases during ring-closing metathesis as a function of the substrate concentration. This is one of the smallest single molecule motors to exhibit catalytically driven motion.

Original language	English (US)
Pages (from-to)	1301-1304
Number of pages	4
Journal	Nanoscale
Volume	5
Issue number	4
DOIs	https://doi.org/10.1039/c2nr32518g
State	Published - Feb 21 2013

All Science Journal Classification (ASJC) codes

General Materials Science

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title = "A catalytically driven organometallic molecular motor",

abstract = "We have observed by NMR spectroscopy that the diffusive movement of a ruthenium-based Grubbs' catalyst increases during ring-closing metathesis as a function of the substrate concentration. This is one of the smallest single molecule motors to exhibit catalytically driven motion.",

author = "Pavlick, {Ryan A.} and Dey, {Krishna K.} and Andrew Sirjoosingh and Alan Benesi and Ayusman Sen",

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AU - Pavlick, Ryan A.

AU - Dey, Krishna K.

AU - Sirjoosingh, Andrew

AU - Benesi, Alan

AU - Sen, Ayusman

PY - 2013/2/21

Y1 - 2013/2/21

N2 - We have observed by NMR spectroscopy that the diffusive movement of a ruthenium-based Grubbs' catalyst increases during ring-closing metathesis as a function of the substrate concentration. This is one of the smallest single molecule motors to exhibit catalytically driven motion.

AB - We have observed by NMR spectroscopy that the diffusive movement of a ruthenium-based Grubbs' catalyst increases during ring-closing metathesis as a function of the substrate concentration. This is one of the smallest single molecule motors to exhibit catalytically driven motion.

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SP - 1301

EP - 1304

JO - Nanoscale

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A catalytically driven organometallic molecular motor

Abstract

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