A Comparison of the Bimolecular and Intramolecular Nucleophilic Catalysis of the Hydrolysis of Substituted Phenyl Acylates by the Dimethylamino Group

Keyphrases

• Hydrolysis 100%
• Acylate 100%
• Dimethylamino Group 100%
• Bimolecular 100%
• Substituted Phenyl 100%
• Nucleophilic Catalysis 100%
• Anions 40%
• Phenylacetate 40%
• Esters 40%
• Carboxyl 40%
• Dimethylamino 40%
• Unimolecular 40%
• Substituted Phenols 20%
• Transition State 20%
• Succinate 20%
• Phenyl 20%
• Butyrate 20%
• Experimental Error 20%
• Valerate 20%
• Trimethylamine 20%
• Acid Hydrolysis 20%
• Linear Free Energy Relationships 20%
• Activation Parameters 20%
• Hammett 20%
• Glutarate 20%
• Constant Parameters 20%
• Apparent Change 20%
• Six-membered 20%
• All-electronic 20%
• H-value 20%
• Substituent Group 20%
• Nucleophilic Displacement 20%
• Five-membered 20%
• Succinic Anhydride 20%

Chemistry

• Nucleophilic Catalysis 100%
• Rate Constant 66%
• Phenylacetate 66%
• Phenyl Acetate 66%
• Transition State 33%
• Succinate 33%
• Linear Free Energy Relationship 33%
• Glutarate 33%
• Trimethylamine 33%
• Succinic Anhydride 33%
• Butyrate 33%
• Valerate 33%