A modular approach to ferroelectric polymers with chemically tunable Curie temperatures and dielectric constants

Yingying Lu; Jason Claude; Bret Neese; Qiming Zhang; Qing Wang

doi:10.1021/ja062306x

A modular approach to ferroelectric polymers with chemically tunable Curie temperatures and dielectric constants

Yingying Lu, Jason Claude, Bret Neese, Qiming Zhang, Qing Wang

Research output: Contribution to journal › Article › peer-review

195 Scopus citations

Abstract

We present a modular approach toward poly(vinylidene fluoride)-based ferroelectric fluoropolymers with high dielectric constants. This strategy is based on a two-step reaction, including the copolymerization of vinylidene fluoride and chlorotrifluoroethylene and a subsequent hydrogenation reaction. The chemical structures and compositions of the resulting polymers can be precisely controlled, leading to tunable Curie temperatures and dielectric constants and a systematical study of structure-property correlations.

Original language	English (US)
Pages (from-to)	8120-8121
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	25
DOIs	https://doi.org/10.1021/ja062306x
State	Published - Jun 28 2006

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja062306x

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abstract = "We present a modular approach toward poly(vinylidene fluoride)-based ferroelectric fluoropolymers with high dielectric constants. This strategy is based on a two-step reaction, including the copolymerization of vinylidene fluoride and chlorotrifluoroethylene and a subsequent hydrogenation reaction. The chemical structures and compositions of the resulting polymers can be precisely controlled, leading to tunable Curie temperatures and dielectric constants and a systematical study of structure-property correlations.",

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AU - Lu, Yingying

AU - Claude, Jason

AU - Neese, Bret

AU - Zhang, Qiming

AU - Wang, Qing

PY - 2006/6/28

Y1 - 2006/6/28

N2 - We present a modular approach toward poly(vinylidene fluoride)-based ferroelectric fluoropolymers with high dielectric constants. This strategy is based on a two-step reaction, including the copolymerization of vinylidene fluoride and chlorotrifluoroethylene and a subsequent hydrogenation reaction. The chemical structures and compositions of the resulting polymers can be precisely controlled, leading to tunable Curie temperatures and dielectric constants and a systematical study of structure-property correlations.

AB - We present a modular approach toward poly(vinylidene fluoride)-based ferroelectric fluoropolymers with high dielectric constants. This strategy is based on a two-step reaction, including the copolymerization of vinylidene fluoride and chlorotrifluoroethylene and a subsequent hydrogenation reaction. The chemical structures and compositions of the resulting polymers can be precisely controlled, leading to tunable Curie temperatures and dielectric constants and a systematical study of structure-property correlations.

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ER -

A modular approach to ferroelectric polymers with chemically tunable Curie temperatures and dielectric constants

Abstract

All Science Journal Classification (ASJC) codes

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