Abstract
A new chiral cyclophane, with a binding cavity defined by the 1,1′-binaphthyl "minor groove" and a strongly π-accepting 4,4-bipyridimum dication, has been synthesized. It self-associates in solution (K = (4.1 ± 1.6) × 102 M-1), and forms charge-transfer complexes with strong π-electron donors.
Original language | English (US) |
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Pages (from-to) | 7599-7602 |
Number of pages | 4 |
Journal | Tetrahedron Letters |
Volume | 36 |
Issue number | 42 |
DOIs | |
State | Published - Oct 16 1995 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Drug Discovery
- Organic Chemistry