A new chiral cyclophane derived from 1,1′-binaphthol and benzylviologen

Nanlin Deng; Vijay Rai Marwaha; Maurie Ei Garcia; Alan Benesi; Thomas E. Mallouk

doi:10.1016/0040-4039(95)01593-7

A new chiral cyclophane derived from 1,1′-binaphthol and benzylviologen

Nanlin Deng
, Vijay Rai Marwaha
, Maurie Ei Garcia
, Alan Benesi
, Thomas E. Mallouk

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A new chiral cyclophane, with a binding cavity defined by the 1,1′-binaphthyl "minor groove" and a strongly π-accepting 4,4-bipyridimum dication, has been synthesized. It self-associates in solution (K = (4.1 ± 1.6) × 10² M^-1), and forms charge-transfer complexes with strong π-electron donors.

Original language	English (US)
Pages (from-to)	7599-7602
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	42
DOIs	https://doi.org/10.1016/0040-4039(95)01593-7
State	Published - Oct 16 1995

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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Cite this

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title = "A new chiral cyclophane derived from 1,1′-binaphthol and benzylviologen",

abstract = "A new chiral cyclophane, with a binding cavity defined by the 1,1′-binaphthyl {"}minor groove{"} and a strongly π-accepting 4,4-bipyridimum dication, has been synthesized. It self-associates in solution (K = (4.1 ± 1.6) × 102 M-1), and forms charge-transfer complexes with strong π-electron donors.",

author = "Nanlin Deng and \{Rai Marwaha\}, Vijay and \{Ei Garcia\}, Maurie and Alan Benesi and Mallouk, \{Thomas E.\}",

year = "1995",

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T1 - A new chiral cyclophane derived from 1,1′-binaphthol and benzylviologen

AU - Deng, Nanlin

AU - Rai Marwaha, Vijay

AU - Ei Garcia, Maurie

AU - Benesi, Alan

AU - Mallouk, Thomas E.

PY - 1995/10/16

Y1 - 1995/10/16

N2 - A new chiral cyclophane, with a binding cavity defined by the 1,1′-binaphthyl "minor groove" and a strongly π-accepting 4,4-bipyridimum dication, has been synthesized. It self-associates in solution (K = (4.1 ± 1.6) × 102 M-1), and forms charge-transfer complexes with strong π-electron donors.

AB - A new chiral cyclophane, with a binding cavity defined by the 1,1′-binaphthyl "minor groove" and a strongly π-accepting 4,4-bipyridimum dication, has been synthesized. It self-associates in solution (K = (4.1 ± 1.6) × 102 M-1), and forms charge-transfer complexes with strong π-electron donors.

UR - https://www.scopus.com/pages/publications/0028787042

UR - https://www.scopus.com/pages/publications/0028787042#tab=citedBy

U2 - 10.1016/0040-4039(95)01593-7

DO - 10.1016/0040-4039(95)01593-7

M3 - Article

AN - SCOPUS:0028787042

SN - 0040-4039

VL - 36

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EP - 7602

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 42

ER -

A new chiral cyclophane derived from 1,1′-binaphthol and benzylviologen

Abstract

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