A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Robert G. Surbella; Lucas C. Ducati; Kristi L. Pellegrini; Bruce K. McNamara; Jochen Autschbach; Jon M. Schwantes; Christopher L. Cahill

doi:10.1039/c7cc05988d

A new Pu(III) coordination geometry in (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·2Cl·2H₂O as obtained via supramolecular assembly in aqueous, high chloride media

Robert G. Surbella, Lucas C. Ducati, Kristi L. Pellegrini, Bruce K. McNamara, Jochen Autschbach, Jon M. Schwantes, Christopher L. Cahill

Mechanical Engineering

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Crystals of a hydrated Pu(iii) chloride, (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·2Cl·2H₂O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl₃(H₂O)₅] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

Original language	English (US)
Pages (from-to)	10816-10819
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	78
DOIs	https://doi.org/10.1039/c7cc05988d
State	Published - 2017

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c7cc05988d

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title = "A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media",

abstract = "Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.",

author = "Surbella, \{Robert G.\} and Ducati, \{Lucas C.\} and Pellegrini, \{Kristi L.\} and McNamara, \{Bruce K.\} and Jochen Autschbach and Schwantes, \{Jon M.\} and Cahill, \{Christopher L.\}",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc05988d",

language = "English (US)",

volume = "53",

pages = "10816--10819",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "78",

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TY - JOUR

T1 - A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

AU - Surbella, Robert G.

AU - Ducati, Lucas C.

AU - Pellegrini, Kristi L.

AU - McNamara, Bruce K.

AU - Autschbach, Jochen

AU - Schwantes, Jon M.

AU - Cahill, Christopher L.

PY - 2017

Y1 - 2017

N2 - Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

AB - Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

UR - https://www.scopus.com/pages/publications/85030312031

UR - https://www.scopus.com/inward/citedby.url?scp=85030312031&partnerID=8YFLogxK

U2 - 10.1039/c7cc05988d

DO - 10.1039/c7cc05988d

M3 - Article

C2 - 28926048

AN - SCOPUS:85030312031

SN - 1359-7345

VL - 53

SP - 10816

EP - 10819

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

A new Pu(III) coordination geometry in (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·2Cl·2H₂O as obtained via supramolecular assembly in aqueous, high chloride media

Abstract

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