A new total synthesis of the marine tunicate alkaloid lepadiformine

Pu Sun; Cuixiang Sun; Steven M. Weinreb

doi:10.1021/ol010179y

A new total synthesis of the marine tunicate alkaloid lepadiformine

Pu Sun, Cuixiang Sun, Steven M. Weinreb

Chemistry

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

(matrix presented) A total synthesis of racemic lepadiformine has been achieved via a route that utilizes as key steps a novel stereocontrolled intramolecular spirocyclization of an allylsilane/N-acyliminium ion and the application of our radical-based methodology for production of N-acylimines from o-aminobenzamides.

Original language	English (US)
Pages (from-to)	3507-3510
Number of pages	4
Journal	Organic Letters
Volume	3
Issue number	22
DOIs	https://doi.org/10.1021/ol010179y
State	Published - Nov 1 2001

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/ol010179y

Cite this

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title = "A new total synthesis of the marine tunicate alkaloid lepadiformine",

abstract = "(matrix presented) A total synthesis of racemic lepadiformine has been achieved via a route that utilizes as key steps a novel stereocontrolled intramolecular spirocyclization of an allylsilane/N-acyliminium ion and the application of our radical-based methodology for production of N-acylimines from o-aminobenzamides.",

author = "Pu Sun and Cuixiang Sun and Weinreb, \{Steven M.\}",

year = "2001",

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AU - Sun, Cuixiang

AU - Weinreb, Steven M.

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N2 - (matrix presented) A total synthesis of racemic lepadiformine has been achieved via a route that utilizes as key steps a novel stereocontrolled intramolecular spirocyclization of an allylsilane/N-acyliminium ion and the application of our radical-based methodology for production of N-acylimines from o-aminobenzamides.

AB - (matrix presented) A total synthesis of racemic lepadiformine has been achieved via a route that utilizes as key steps a novel stereocontrolled intramolecular spirocyclization of an allylsilane/N-acyliminium ion and the application of our radical-based methodology for production of N-acylimines from o-aminobenzamides.

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JO - Organic Letters

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A new total synthesis of the marine tunicate alkaloid lepadiformine

Abstract

All Science Journal Classification (ASJC) codes

UN SDGs

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