A Route towards Fabrication of Functional Ceramic/Polymer Nanocomposite Devices Using the Cold Sintering Process

Sinan Dursun; Kosuke Tsuji; Sun Hwi Bang; Arnaud Ndayishimiye; Clive A. Randall

doi:10.1021/acsaelm.0c00225

A Route towards Fabrication of Functional Ceramic/Polymer Nanocomposite Devices Using the Cold Sintering Process

Sinan Dursun, Kosuke Tsuji, Sun Hwi Bang, Arnaud Ndayishimiye, Clive A. Randall

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The use of low-temperature and energy-efficient techniques to fabricate composites with tailored interfaces is currently a topic of growing interest. This study reports the proof of concept of a process to fabricate functional multilayer varistor (MLV) devices below 150 °C. In this MLV device, a small volume fraction of polyetherimide polymer is used to engineer ZnO grain boundaries, and the multilayer composite is cofired with base metal internal electrodes via the cold sintering cofired ceramic (CSCC). The resulting dense nanocomposite MLV and controlled nonlinear current-voltage response of the device confirmed the potential of CSCC. This work also opens up the possibility to fabricate multilayer devices for other types of applications.

Original language	English (US)
Pages (from-to)	1917-1924
Number of pages	8
Journal	ACS Applied Electronic Materials
Volume	2
Issue number	7
DOIs	https://doi.org/10.1021/acsaelm.0c00225
State	Published - Jul 28 2020

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Materials Chemistry
Electrochemistry

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10.1021/acsaelm.0c00225

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title = "A Route towards Fabrication of Functional Ceramic/Polymer Nanocomposite Devices Using the Cold Sintering Process",

abstract = "The use of low-temperature and energy-efficient techniques to fabricate composites with tailored interfaces is currently a topic of growing interest. This study reports the proof of concept of a process to fabricate functional multilayer varistor (MLV) devices below 150 °C. In this MLV device, a small volume fraction of polyetherimide polymer is used to engineer ZnO grain boundaries, and the multilayer composite is cofired with base metal internal electrodes via the cold sintering cofired ceramic (CSCC). The resulting dense nanocomposite MLV and controlled nonlinear current-voltage response of the device confirmed the potential of CSCC. This work also opens up the possibility to fabricate multilayer devices for other types of applications.",

author = "Sinan Dursun and Kosuke Tsuji and Bang, {Sun Hwi} and Arnaud Ndayishimiye and Randall, {Clive A.}",

note = "Funding Information: This material is based on the work supported by the National Science Foundation, as part of the Center for Dielectrics and Piezoelectrics under grant nos. IIP-1361571 and 1361503, and IIP-1841453 and 1841466. We wish to thank Shoei Chemical Inc. for supplying copper powders, Empower Materials for supplying QPAC binder polymers, and SABIC for supplying the PEI polymer. Any opinions, findings, conclusions, or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the Foundation. The authors also would like to acknowledge Steve Perini, Jeff Long, Julie Anderson, Manuel Villalpando, and Ke Wang for their technical support during this study. Publisher Copyright: {\textcopyright} 2020 American Chemical Society.",

year = "2020",

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doi = "10.1021/acsaelm.0c00225",

language = "English (US)",

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AU - Dursun, Sinan

AU - Tsuji, Kosuke

AU - Bang, Sun Hwi

AU - Ndayishimiye, Arnaud

AU - Randall, Clive A.

N1 - Funding Information: This material is based on the work supported by the National Science Foundation, as part of the Center for Dielectrics and Piezoelectrics under grant nos. IIP-1361571 and 1361503, and IIP-1841453 and 1841466. We wish to thank Shoei Chemical Inc. for supplying copper powders, Empower Materials for supplying QPAC binder polymers, and SABIC for supplying the PEI polymer. Any opinions, findings, conclusions, or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the Foundation. The authors also would like to acknowledge Steve Perini, Jeff Long, Julie Anderson, Manuel Villalpando, and Ke Wang for their technical support during this study. Publisher Copyright: © 2020 American Chemical Society.

PY - 2020/7/28

Y1 - 2020/7/28

N2 - The use of low-temperature and energy-efficient techniques to fabricate composites with tailored interfaces is currently a topic of growing interest. This study reports the proof of concept of a process to fabricate functional multilayer varistor (MLV) devices below 150 °C. In this MLV device, a small volume fraction of polyetherimide polymer is used to engineer ZnO grain boundaries, and the multilayer composite is cofired with base metal internal electrodes via the cold sintering cofired ceramic (CSCC). The resulting dense nanocomposite MLV and controlled nonlinear current-voltage response of the device confirmed the potential of CSCC. This work also opens up the possibility to fabricate multilayer devices for other types of applications.

AB - The use of low-temperature and energy-efficient techniques to fabricate composites with tailored interfaces is currently a topic of growing interest. This study reports the proof of concept of a process to fabricate functional multilayer varistor (MLV) devices below 150 °C. In this MLV device, a small volume fraction of polyetherimide polymer is used to engineer ZnO grain boundaries, and the multilayer composite is cofired with base metal internal electrodes via the cold sintering cofired ceramic (CSCC). The resulting dense nanocomposite MLV and controlled nonlinear current-voltage response of the device confirmed the potential of CSCC. This work also opens up the possibility to fabricate multilayer devices for other types of applications.

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A Route towards Fabrication of Functional Ceramic/Polymer Nanocomposite Devices Using the Cold Sintering Process

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