A study of thermal activation of N-nitrosoamides

Ron W. Darbeau; Edson V. Perez; Martin Brantley

doi:10.2174/157017806778700051

A study of thermal activation of N-nitrosoamides

Ron W. Darbeau, Edson V. Perez, Martin Brantley

Penn State Altoona

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Abstract

N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from ΔH* and ΔS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester.

Original language	English (US)
Pages (from-to)	689-698
Number of pages	10
Journal	Letters in Organic Chemistry
Volume	3
Issue number	9
DOIs	https://doi.org/10.2174/157017806778700051
State	Published - Sep 2006

All Science Journal Classification (ASJC) codes

Biochemistry
Organic Chemistry

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abstract = "N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from ΔH* and ΔS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester.",

author = "Darbeau, {Ron W.} and Perez, {Edson V.} and Martin Brantley",

year = "2006",

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AU - Perez, Edson V.

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AB - N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from ΔH* and ΔS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester.

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A study of thermal activation of N-nitrosoamides

Abstract

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