A study of thermal activation of N-nitrosoamides

Ron W. Darbeau; Edson V. Perez; Martin Brantley

doi:10.2174/157017806778700051

A study of thermal activation of N-nitrosoamides

Ron W. Darbeau
, Edson V. Perez
, Martin Brantley

Penn State Altoona

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from ΔH* and ΔS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester.

Original language	English (US)
Pages (from-to)	689-698
Number of pages	10
Journal	Letters in Organic Chemistry
Volume	3
Issue number	9
DOIs	https://doi.org/10.2174/157017806778700051
State	Published - Sep 2006

All Science Journal Classification (ASJC) codes

Biochemistry
Organic Chemistry

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10.2174/157017806778700051

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title = "A study of thermal activation of N-nitrosoamides",

abstract = "N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from ΔH* and ΔS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester.",

author = "Darbeau, \{Ron W.\} and Perez, \{Edson V.\} and Martin Brantley",

year = "2006",

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doi = "10.2174/157017806778700051",

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pages = "689--698",

journal = "Letters in Organic Chemistry",

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AU - Perez, Edson V.

AU - Brantley, Martin

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N2 - N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from ΔH* and ΔS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester.

AB - N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from ΔH* and ΔS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester.

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UR - https://www.scopus.com/pages/publications/33750441122#tab=citedBy

U2 - 10.2174/157017806778700051

DO - 10.2174/157017806778700051

M3 - Article

AN - SCOPUS:33750441122

SN - 1570-1786

VL - 3

SP - 689

EP - 698

JO - Letters in Organic Chemistry

JF - Letters in Organic Chemistry

IS - 9

ER -

A study of thermal activation of N-nitrosoamides

Abstract

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