A Thermodynamic Approach to Guide Reactive Element Doping: Hf Additions to NiCrAl

Thomas Gheno, Bi Cheng Zhou, Austin Ross, Xuan Liu, Greta Lindwall, Zi Kui Liu, Brian Gleeson

Research output: Contribution to journalArticlepeer-review

9 Scopus citations


A method based on thermodynamic modeling was developed to determine optimal amounts of Hf additions to Al2O3-forming, γ-γ′ NiCrAl alloys. The alloy ability to maintain Hf in solution was set by the Hf concentration required to form HfO2 at the oxygen activity defined by the alloy/Al2O3 equilibrium. This Hf tolerance decreased with increasing temperature and increased with increasing γ′ fraction. The latter was due to the higher solubility of Hf in γ′, compared to γ. The validity of the procedure was evaluated by oxidizing a series of NiCrAl–Hf alloys in dry air at 1000–1200 °C. The experimental results followed the predicted trends, although the Hf tolerance tended to be overestimated. The applicability of the criterion, and potential routes for improved predictability, were discussed by considering the influence of the compositional changes occurring at the metal surface during the transient and steady-state stages of the oxidation process.

Original languageEnglish (US)
Pages (from-to)297-310
Number of pages14
JournalOxidation of Metals
Issue number3-4
StatePublished - Apr 1 2017

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry


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