Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation

Keyphrases

• Active Sites 100%
• Co-adsorption 100%
• Intermetallics 100%
• Precise Identification 100%
• Olefin Hydrogenation 100%
• Site Isolation 100%
• Elementary Reaction Mechanism 100%
• Microkinetic Model 66%
• Elementary Reaction 66%
• Isolated Site 66%
• Reaction Rate 33%
• Temperature Effect 33%
• Trimer 33%
• Reaction Chemistry 33%
• Density Functional Calculations 33%
• Density Functional Theory 33%
• Mechanistic Understanding 33%
• Kinetic Measurements 33%
• Steady-state Distribution 33%
• Reaction Order 33%
• Intermetallic Phases 33%
• Brass 33%
• Synthetic Control Method 33%
• Site Competition 33%
• Kinetic Behavior 33%
• Coverage Effects 33%
• Heterogeneous Catalyst 33%
• Adsorption Configuration 33%
• Ethylene Hydrogenation 33%
• Acute Temperature 33%
• PdZn 33%
• Experimental Kinetics 33%
• Degree of Rate Control 33%

Chemistry

• Chemistry 100%
• Alkene 100%
• Hydrogenation 100%
• microkinetic model 100%
• Intermetallic Compound 100%
• Hydrogen 50%
• Ethylene 50%
• Density Functional Theory 50%
• Monomer 50%
• Rate Constant 50%
• Kinetics Measurement 50%
• Reaction Order 50%
• Heterogeneous Catalyst 50%
• Density Functional Theory 50%

Chemical Engineering

• Olefin 100%
• Hydrogenation 100%
• Co-adsorption 100%
• Chemical Kinetics Characteristics 33%
• Ethylene 33%