Adsorption spectroscopy by polariton-induced desorption (ASPID)

Jesús Reyes; Frank O. Goodman; Milton W. Cole

doi:10.1016/0039-6028(85)90463-7

Adsorption spectroscopy by polariton-induced desorption (ASPID)

Jesús Reyes, Frank O. Goodman, Milton W. Cole

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A new spectroscopic technique is proposed as a means of determining the energy and momentum of adsorbed atoms and molecules. The method, abbreviated to ASPID (adsorption spectroscopy by polariton-induced desorption), uses surface phonon polaritons (SPPs) to desorb atoms. Because one may create nearly-monoenergetic SPPs, the binding energy range is determined directly from the spectrum of final energies. A kinematical analysis may be used to analyze adatom momenta, and hence band structures. The angular distribution of the SPP-desorbed atoms may be used to monitor adsorbed-film temperature. We provide an estimate of the SPP desorption rate, and conclude that the proposed experiment is feasible.

Original language	English (US)
Pages (from-to)	221-250
Number of pages	30
Journal	Surface Science
Volume	151
Issue number	1
DOIs	https://doi.org/10.1016/0039-6028(85)90463-7
State	Published - Mar 1 1985

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

Access to Document

10.1016/0039-6028(85)90463-7

Cite this

@article{1b590509357845eba8280254a4b8e329,

title = "Adsorption spectroscopy by polariton-induced desorption (ASPID)",

abstract = "A new spectroscopic technique is proposed as a means of determining the energy and momentum of adsorbed atoms and molecules. The method, abbreviated to ASPID (adsorption spectroscopy by polariton-induced desorption), uses surface phonon polaritons (SPPs) to desorb atoms. Because one may create nearly-monoenergetic SPPs, the binding energy range is determined directly from the spectrum of final energies. A kinematical analysis may be used to analyze adatom momenta, and hence band structures. The angular distribution of the SPP-desorbed atoms may be used to monitor adsorbed-film temperature. We provide an estimate of the SPP desorption rate, and conclude that the proposed experiment is feasible.",

author = "Jes{\'u}s Reyes and Goodman, {Frank O.} and {W. Cole}, Milton",

note = "Funding Information: The authors acknowledge the benefit of useful discussions with Drs. D.R. Frankl, P.H. Cutler, J.W. Gadzuk, R. Fuchs, D.L. Mills, G. Benedek, and I. Romero. This work was supported by NSF Grant No. DMR-8113262, by CONACyT and DGICSA-SEP (Mexico), and by the Natural Sciences and Engineering Research Council of Canada, under Grant No. A6282.",

year = "1985",

month = mar,

day = "1",

doi = "10.1016/0039-6028(85)90463-7",

language = "English (US)",

volume = "151",

pages = "221--250",

journal = "Surface Science",

issn = "0039-6028",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Adsorption spectroscopy by polariton-induced desorption (ASPID)

AU - Reyes, Jesús

AU - Goodman, Frank O.

AU - W. Cole, Milton

N1 - Funding Information: The authors acknowledge the benefit of useful discussions with Drs. D.R. Frankl, P.H. Cutler, J.W. Gadzuk, R. Fuchs, D.L. Mills, G. Benedek, and I. Romero. This work was supported by NSF Grant No. DMR-8113262, by CONACyT and DGICSA-SEP (Mexico), and by the Natural Sciences and Engineering Research Council of Canada, under Grant No. A6282.

PY - 1985/3/1

Y1 - 1985/3/1

N2 - A new spectroscopic technique is proposed as a means of determining the energy and momentum of adsorbed atoms and molecules. The method, abbreviated to ASPID (adsorption spectroscopy by polariton-induced desorption), uses surface phonon polaritons (SPPs) to desorb atoms. Because one may create nearly-monoenergetic SPPs, the binding energy range is determined directly from the spectrum of final energies. A kinematical analysis may be used to analyze adatom momenta, and hence band structures. The angular distribution of the SPP-desorbed atoms may be used to monitor adsorbed-film temperature. We provide an estimate of the SPP desorption rate, and conclude that the proposed experiment is feasible.

AB - A new spectroscopic technique is proposed as a means of determining the energy and momentum of adsorbed atoms and molecules. The method, abbreviated to ASPID (adsorption spectroscopy by polariton-induced desorption), uses surface phonon polaritons (SPPs) to desorb atoms. Because one may create nearly-monoenergetic SPPs, the binding energy range is determined directly from the spectrum of final energies. A kinematical analysis may be used to analyze adatom momenta, and hence band structures. The angular distribution of the SPP-desorbed atoms may be used to monitor adsorbed-film temperature. We provide an estimate of the SPP desorption rate, and conclude that the proposed experiment is feasible.

UR - http://www.scopus.com/inward/record.url?scp=46549104124&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=46549104124&partnerID=8YFLogxK

U2 - 10.1016/0039-6028(85)90463-7

DO - 10.1016/0039-6028(85)90463-7

M3 - Article

AN - SCOPUS:46549104124

SN - 0039-6028

VL - 151

SP - 221

EP - 250

JO - Surface Science

JF - Surface Science

IS - 1

ER -

Adsorption spectroscopy by polariton-induced desorption (ASPID)

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this