Advances in unit operations and materials for the Cu–Cl cycle of hydrogen production

G. F. Naterer; S. Suppiah; M. A. Rosen; K. Gabriel; I. Dincer; O. A. Jianu; Z. Wang; E. B. Easton; B. M. Ikeda; G. Rizvi; I. Pioro; K. Pope; J. Mostaghimi; S. N. Lvov

doi:10.1016/j.ijhydene.2017.03.133

Advances in unit operations and materials for the Cu–Cl cycle of hydrogen production

G. F. Naterer
, S. Suppiah
, M. A. Rosen
, K. Gabriel
, I. Dincer
, O. A. Jianu
, Z. Wang
, E. B. Easton
, B. M. Ikeda
, G. Rizvi
, I. Pioro
, K. Pope
, J. Mostaghimi
, S. N. Lvov

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

This paper presents recent advances by an international team of five countries – Canada, U.S., China, Slovenia and Romania – on the development and scale-up of the copper–chlorine (Cu–Cl) cycle for thermochemical hydrogen production using nuclear or solar energy. Electrochemical cell analysis and membrane characterization for the CuCl/HCl electrolysis process are presented. Constituent solubility in the ternary CuCl/HCl/H₂O system and XRD measurements are reported in regards to the CuCl₂ crystallization process. Materials corrosion in high temperature copper chloride salts and performance of coatings of reactor surface alloys are examined. Finally, system integration is examined, with respect to scale-up of unit operations, cascaded heat pumps for heat upgrading, and linkage of heat exchangers with solar and nuclear plants.

Original language	English (US)
Pages (from-to)	15708-15723
Number of pages	16
Journal	International Journal of Hydrogen Energy
Volume	42
Issue number	24
DOIs	https://doi.org/10.1016/j.ijhydene.2017.03.133
State	Published - Jun 15 2017

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

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10.1016/j.ijhydene.2017.03.133

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Naterer, G. F., Suppiah, S., Rosen, M. A., Gabriel, K., Dincer, I., Jianu, O. A., Wang, Z., Easton, E. B., Ikeda, B. M., Rizvi, G., Pioro, I., Pope, K., Mostaghimi, J., & Lvov, S. N. (2017). Advances in unit operations and materials for the Cu–Cl cycle of hydrogen production. International Journal of Hydrogen Energy, 42(24), 15708-15723. https://doi.org/10.1016/j.ijhydene.2017.03.133

@article{40a767eea3534410881d7d04ff4387fa,

title = "Advances in unit operations and materials for the Cu–Cl cycle of hydrogen production",

abstract = "This paper presents recent advances by an international team of five countries – Canada, U.S., China, Slovenia and Romania – on the development and scale-up of the copper–chlorine (Cu–Cl) cycle for thermochemical hydrogen production using nuclear or solar energy. Electrochemical cell analysis and membrane characterization for the CuCl/HCl electrolysis process are presented. Constituent solubility in the ternary CuCl/HCl/H2O system and XRD measurements are reported in regards to the CuCl2 crystallization process. Materials corrosion in high temperature copper chloride salts and performance of coatings of reactor surface alloys are examined. Finally, system integration is examined, with respect to scale-up of unit operations, cascaded heat pumps for heat upgrading, and linkage of heat exchangers with solar and nuclear plants.",

author = "Naterer, \{G. F.\} and S. Suppiah and Rosen, \{M. A.\} and K. Gabriel and I. Dincer and Jianu, \{O. A.\} and Z. Wang and Easton, \{E. B.\} and Ikeda, \{B. M.\} and G. Rizvi and I. Pioro and K. Pope and J. Mostaghimi and Lvov, \{S. N.\}",

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doi = "10.1016/j.ijhydene.2017.03.133",

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Naterer, GF, Suppiah, S, Rosen, MA, Gabriel, K, Dincer, I, Jianu, OA, Wang, Z, Easton, EB, Ikeda, BM, Rizvi, G, Pioro, I, Pope, K, Mostaghimi, J & Lvov, SN 2017, 'Advances in unit operations and materials for the Cu–Cl cycle of hydrogen production', International Journal of Hydrogen Energy, vol. 42, no. 24, pp. 15708-15723. https://doi.org/10.1016/j.ijhydene.2017.03.133

TY - JOUR

T1 - Advances in unit operations and materials for the Cu–Cl cycle of hydrogen production

AU - Naterer, G. F.

AU - Suppiah, S.

AU - Rosen, M. A.

AU - Gabriel, K.

AU - Dincer, I.

AU - Jianu, O. A.

AU - Wang, Z.

AU - Easton, E. B.

AU - Ikeda, B. M.

AU - Rizvi, G.

AU - Pioro, I.

AU - Pope, K.

AU - Mostaghimi, J.

AU - Lvov, S. N.

PY - 2017/6/15

Y1 - 2017/6/15

N2 - This paper presents recent advances by an international team of five countries – Canada, U.S., China, Slovenia and Romania – on the development and scale-up of the copper–chlorine (Cu–Cl) cycle for thermochemical hydrogen production using nuclear or solar energy. Electrochemical cell analysis and membrane characterization for the CuCl/HCl electrolysis process are presented. Constituent solubility in the ternary CuCl/HCl/H2O system and XRD measurements are reported in regards to the CuCl2 crystallization process. Materials corrosion in high temperature copper chloride salts and performance of coatings of reactor surface alloys are examined. Finally, system integration is examined, with respect to scale-up of unit operations, cascaded heat pumps for heat upgrading, and linkage of heat exchangers with solar and nuclear plants.

AB - This paper presents recent advances by an international team of five countries – Canada, U.S., China, Slovenia and Romania – on the development and scale-up of the copper–chlorine (Cu–Cl) cycle for thermochemical hydrogen production using nuclear or solar energy. Electrochemical cell analysis and membrane characterization for the CuCl/HCl electrolysis process are presented. Constituent solubility in the ternary CuCl/HCl/H2O system and XRD measurements are reported in regards to the CuCl2 crystallization process. Materials corrosion in high temperature copper chloride salts and performance of coatings of reactor surface alloys are examined. Finally, system integration is examined, with respect to scale-up of unit operations, cascaded heat pumps for heat upgrading, and linkage of heat exchangers with solar and nuclear plants.

UR - https://www.scopus.com/pages/publications/85020056763

UR - https://www.scopus.com/pages/publications/85020056763#tab=citedBy

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DO - 10.1016/j.ijhydene.2017.03.133

M3 - Article

AN - SCOPUS:85020056763

SN - 0360-3199

VL - 42

SP - 15708

EP - 15723

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 24

ER -

Advances in unit operations and materials for the Cu–Cl cycle of hydrogen production

Abstract

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