TY - JOUR
T1 - Alkylated intermediate of cyclo-alkanes for stabilization of paraffinic jet fuels under pyrolytic conditions
AU - Andrésen, John M.
AU - Strohm, James J.
AU - Song, Chunshan
PY - 1999
Y1 - 1999
N2 - The thermal stability of linear alkanes, such as tetradecane, in the pyrolytic regime is enhanced by the addition of cyclo-akanes, in particular decalin. Based on the product distribution from the thermal stressing of their mixtures, decalin was found to target primary radicals, particularly by a sharp reduction in the n-alkane products in relation to that of the 1-alkene. This thermal interaction has been further examined by GC/MS analysis, which revealed the formation of alkylated intermediates of decalin that stabilizes the paraffinic species in the pyrolytic regime.
AB - The thermal stability of linear alkanes, such as tetradecane, in the pyrolytic regime is enhanced by the addition of cyclo-akanes, in particular decalin. Based on the product distribution from the thermal stressing of their mixtures, decalin was found to target primary radicals, particularly by a sharp reduction in the n-alkane products in relation to that of the 1-alkene. This thermal interaction has been further examined by GC/MS analysis, which revealed the formation of alkylated intermediates of decalin that stabilizes the paraffinic species in the pyrolytic regime.
UR - http://www.scopus.com/inward/record.url?scp=0032762591&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0032762591&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0032762591
SN - 0569-3772
VL - 44
SP - 562
EP - 564
JO - ACS Division of Fuel Chemistry, Preprints
JF - ACS Division of Fuel Chemistry, Preprints
IS - 3
ER -