Alkynyliodonium salts in organic synthesis. Application to the preparation of the tricyclic core of (±)-halichlorine

Ken S. Feldman; Angela L. Perkins; Katherine M. Masters

doi:10.1021/jo0487911

Alkynyliodonium salts in organic synthesis. Application to the preparation of the tricyclic core of (±)-halichlorine

Ken S. Feldman, Angela L. Perkins, Katherine M. Masters

Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The tricyclic core of halichlorine has been synthesized through the use of an alkynyliodonium salt/ alkylidenecarbene/1,5 C-H insertion sequence that sets the pivotal quaternary center in the target.

Original language	English (US)
Pages (from-to)	7928-7932
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	69
Issue number	23
DOIs	https://doi.org/10.1021/jo0487911
State	Published - Nov 12 2004

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo0487911

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title = "Alkynyliodonium salts in organic synthesis. Application to the preparation of the tricyclic core of (±)-halichlorine",

abstract = "The tricyclic core of halichlorine has been synthesized through the use of an alkynyliodonium salt/ alkylidenecarbene/1,5 C-H insertion sequence that sets the pivotal quaternary center in the target.",

author = "Feldman, {Ken S.} and Perkins, {Angela L.} and Masters, {Katherine M.}",

year = "2004",

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AU - Feldman, Ken S.

AU - Perkins, Angela L.

AU - Masters, Katherine M.

PY - 2004/11/12

Y1 - 2004/11/12

N2 - The tricyclic core of halichlorine has been synthesized through the use of an alkynyliodonium salt/ alkylidenecarbene/1,5 C-H insertion sequence that sets the pivotal quaternary center in the target.

AB - The tricyclic core of halichlorine has been synthesized through the use of an alkynyliodonium salt/ alkylidenecarbene/1,5 C-H insertion sequence that sets the pivotal quaternary center in the target.

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Alkynyliodonium salts in organic synthesis. Application to the preparation of the tricyclic core of (±)-halichlorine

Abstract

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