Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy

E. Sauvage; N. Plucktaveesak; R. H. Colby; D. A. Amos; B. Antalek; K. M. Schroeder; J. S. Tan

doi:10.1002/polb.20201

Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy

E. Sauvage, N. Plucktaveesak, R. H. Colby, D. A. Amos, B. Antalek, K. M. Schroeder, J. S. Tan

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The dilute solution behavior of several alternating copolymers of maleic acid was characterized by static and dynamic light scattering, intrinsic viscosity, and pulsed-gradient spin-echo NMR spectroscopy. The copolymer modified with the longer chain n-decyl forms stable large intermolecular aggregates containing 33 chains/aggregate. The copolymer of maleic acid-sodium salt and di-siobutylene (DINMA-Na) possesed a similar salting-out concentration as SMA-Na. The scattering results, PGSE, NMR diffusion measurements indicate only one diffusion coefficient consistent with the motion of single isolated chains.

Original language	English (US)
Pages (from-to)	3584-3597
Number of pages	14
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	42
Issue number	19
DOIs	https://doi.org/10.1002/polb.20201
State	Published - Oct 1 2004

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/polb.20201

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Sauvage, E., Plucktaveesak, N., Colby, R. H., Amos, D. A., Antalek, B., Schroeder, K. M., & Tan, J. S. (2004). Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy. Journal of Polymer Science, Part B: Polymer Physics, 42(19), 3584-3597. https://doi.org/10.1002/polb.20201

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title = "Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy",

abstract = "The dilute solution behavior of several alternating copolymers of maleic acid was characterized by static and dynamic light scattering, intrinsic viscosity, and pulsed-gradient spin-echo NMR spectroscopy. The copolymer modified with the longer chain n-decyl forms stable large intermolecular aggregates containing 33 chains/aggregate. The copolymer of maleic acid-sodium salt and di-siobutylene (DINMA-Na) possesed a similar salting-out concentration as SMA-Na. The scattering results, PGSE, NMR diffusion measurements indicate only one diffusion coefficient consistent with the motion of single isolated chains.",

author = "E. Sauvage and N. Plucktaveesak and Colby, {R. H.} and Amos, {D. A.} and B. Antalek and Schroeder, {K. M.} and Tan, {J. S.}",

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doi = "10.1002/polb.20201",

language = "English (US)",

volume = "42",

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Sauvage, E, Plucktaveesak, N, Colby, RH, Amos, DA, Antalek, B, Schroeder, KM & Tan, JS 2004, 'Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy', Journal of Polymer Science, Part B: Polymer Physics, vol. 42, no. 19, pp. 3584-3597. https://doi.org/10.1002/polb.20201

Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy. / Sauvage, E.; Plucktaveesak, N.; Colby, R. H. et al.
In: Journal of Polymer Science, Part B: Polymer Physics, Vol. 42, No. 19, 01.10.2004, p. 3584-3597.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy

AU - Sauvage, E.

AU - Plucktaveesak, N.

AU - Colby, R. H.

AU - Amos, D. A.

AU - Antalek, B.

AU - Schroeder, K. M.

AU - Tan, J. S.

PY - 2004/10/1

Y1 - 2004/10/1

N2 - The dilute solution behavior of several alternating copolymers of maleic acid was characterized by static and dynamic light scattering, intrinsic viscosity, and pulsed-gradient spin-echo NMR spectroscopy. The copolymer modified with the longer chain n-decyl forms stable large intermolecular aggregates containing 33 chains/aggregate. The copolymer of maleic acid-sodium salt and di-siobutylene (DINMA-Na) possesed a similar salting-out concentration as SMA-Na. The scattering results, PGSE, NMR diffusion measurements indicate only one diffusion coefficient consistent with the motion of single isolated chains.

AB - The dilute solution behavior of several alternating copolymers of maleic acid was characterized by static and dynamic light scattering, intrinsic viscosity, and pulsed-gradient spin-echo NMR spectroscopy. The copolymer modified with the longer chain n-decyl forms stable large intermolecular aggregates containing 33 chains/aggregate. The copolymer of maleic acid-sodium salt and di-siobutylene (DINMA-Na) possesed a similar salting-out concentration as SMA-Na. The scattering results, PGSE, NMR diffusion measurements indicate only one diffusion coefficient consistent with the motion of single isolated chains.

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JO - Journal of Polymer Science, Part B: Polymer Physics

JF - Journal of Polymer Science, Part B: Polymer Physics

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Amphiphilic maleic acid-containing alternating copolymers - 2. Dilute solution characterization by light scattering, intrinsic viscosity, and PGSE NMR spectroscopy

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