An inexpensive, widely available material for 4 wt % reversible hydrogen storage near room temperature

Tod A. Pascal, Christopher Boxe, William A. Goddard

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

The search for cheap, renewable energy sources to replace fossil fuels has identified hydrogen gas (H2) as the most promising, particularly for transportation. However, despite intense research efforts to find reliable storage materials, current practical technologies store only 1.3 wt % H 2 at 270 K, far short of the U.S. DOE targets. We report that hexagonal ice, the ordinary form of ice in snow, may be an efficient hydrogen storage material, achieving 3.8 wt % H2 storage and 42 g L -1 at 150K and that after loading at 150 K, the 3.8 wt % H 2 can be kept at 270 K and then released upon heating by a few degrees Kelvin. This leads us to propose the ice-fixed melt-triggered (IFMT) strategy for hydrogen storage and utilization with ice as the median.

Original languageEnglish (US)
Pages (from-to)1417-1420
Number of pages4
JournalJournal of Physical Chemistry Letters
Volume2
Issue number12
DOIs
StatePublished - Jun 16 2011

All Science Journal Classification (ASJC) codes

  • General Materials Science
  • Physical and Theoretical Chemistry

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