Artificial photosynthesis in lamellar assemblies of metal poly(pyridyl) complexes and metalloporphyrins

David M. Kaschak; Stacy A. Johnson; Chad C. Waraksa; Jessica Pogue; Thomas E. Mallouk

doi:10.1016/s0010-8545(99)00025-9

Artificial photosynthesis in lamellar assemblies of metal poly(pyridyl) complexes and metalloporphyrins

David M. Kaschak, Stacy A. Johnson, Chad C. Waraksa, Jessica Pogue, Thomas E. Mallouk

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

Multilayer films composed of inorganic colloids (α-zirconium phosphate or HTiNbO₅) and organic polycations can be grown in almost any desired sequence on surfaces by electrostatic self-assembly. Control of the edge chemistry of the anionic sheets is essential to the preparation of well organized monolayers and multilayers. Examples are given of layer sequences that incorporate electron donors and acceptors, which undergo photoinduced electron transfer reactions across inorganic spacer layers. Similar stacking sequences can be used to couple light harvesting assemblies, containing energy donors and acceptors, to electron donor-acceptor dyads.

Original language	English (US)
Pages (from-to)	403-416
Number of pages	14
Journal	Coordination Chemistry Reviews
Volume	185-186
DOIs	https://doi.org/10.1016/s0010-8545(99)00025-9
State	Published - May 1999

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/s0010-8545(99)00025-9

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title = "Artificial photosynthesis in lamellar assemblies of metal poly(pyridyl) complexes and metalloporphyrins",

abstract = "Multilayer films composed of inorganic colloids (α-zirconium phosphate or HTiNbO5) and organic polycations can be grown in almost any desired sequence on surfaces by electrostatic self-assembly. Control of the edge chemistry of the anionic sheets is essential to the preparation of well organized monolayers and multilayers. Examples are given of layer sequences that incorporate electron donors and acceptors, which undergo photoinduced electron transfer reactions across inorganic spacer layers. Similar stacking sequences can be used to couple light harvesting assemblies, containing energy donors and acceptors, to electron donor-acceptor dyads.",

author = "Kaschak, {David M.} and Johnson, {Stacy A.} and Waraksa, {Chad C.} and Jessica Pogue and Mallouk, {Thomas E.}",

note = "Funding Information: This work was supported by the Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy, under contract DE-FG02-93ER14374. We thank Dr Mary Kunze of the Center for Quantitative Cell Analysis, Pennsylvania State University, for assistance with the fluorescence microscopy experiments. ",

year = "1999",

month = may,

doi = "10.1016/s0010-8545(99)00025-9",

language = "English (US)",

volume = "185-186",

pages = "403--416",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Artificial photosynthesis in lamellar assemblies of metal poly(pyridyl) complexes and metalloporphyrins

AU - Kaschak, David M.

AU - Johnson, Stacy A.

AU - Waraksa, Chad C.

AU - Pogue, Jessica

AU - Mallouk, Thomas E.

N1 - Funding Information: This work was supported by the Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy, under contract DE-FG02-93ER14374. We thank Dr Mary Kunze of the Center for Quantitative Cell Analysis, Pennsylvania State University, for assistance with the fluorescence microscopy experiments.

PY - 1999/5

Y1 - 1999/5

N2 - Multilayer films composed of inorganic colloids (α-zirconium phosphate or HTiNbO5) and organic polycations can be grown in almost any desired sequence on surfaces by electrostatic self-assembly. Control of the edge chemistry of the anionic sheets is essential to the preparation of well organized monolayers and multilayers. Examples are given of layer sequences that incorporate electron donors and acceptors, which undergo photoinduced electron transfer reactions across inorganic spacer layers. Similar stacking sequences can be used to couple light harvesting assemblies, containing energy donors and acceptors, to electron donor-acceptor dyads.

AB - Multilayer films composed of inorganic colloids (α-zirconium phosphate or HTiNbO5) and organic polycations can be grown in almost any desired sequence on surfaces by electrostatic self-assembly. Control of the edge chemistry of the anionic sheets is essential to the preparation of well organized monolayers and multilayers. Examples are given of layer sequences that incorporate electron donors and acceptors, which undergo photoinduced electron transfer reactions across inorganic spacer layers. Similar stacking sequences can be used to couple light harvesting assemblies, containing energy donors and acceptors, to electron donor-acceptor dyads.

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JO - Coordination Chemistry Reviews

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Artificial photosynthesis in lamellar assemblies of metal poly(pyridyl) complexes and metalloporphyrins

Abstract

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