Bimetallic Fe-Co catalysts for CO2 hydrogenation to higher hydrocarbons

Ratchprapa Satthawong; Naoto Koizumi; Chunshan Song; Pattarapan Prasassarakich

doi:10.1016/j.jcou.2013.10.002

Bimetallic Fe-Co catalysts for CO₂ hydrogenation to higher hydrocarbons

Ratchprapa Satthawong
, Naoto Koizumi
, Chunshan Song
, Pattarapan Prasassarakich

Research output: Contribution to journal › Article › peer-review

227 Scopus citations

Abstract

This paper reports on Fe-Co bimetallic catalysts that are active and selective for synthesis of olefin-rich C₂⁺ hydrocarbons from CO₂ hydrogenation. The combination of Fe and a small amount of Co led to a dramatic bimetallic promotion of C₂⁺ hydrocarbons synthesis in CO₂ hydrogenation on Fe-Co/Al ₂O₃ catalyst with 15 wt% total metal loading. The addition of K to Fe-Co/Al₂O₃ catalyst further improved the formation rate of C₂⁺ hydrocarbons as well as their olefin contents, while it suppressed CH₄ formation significantly. Olefin-rich C₂⁺ hydrocarbons was successfully synthesized using K-promoted Fe-Co/Al₂O₃ catalysts with high K loadings (Co/(Co + Fe) = 0.17 atom atom^-1, K/Fe ≥ 0.5 atom atom^-1) using CO₂ as a carbon source.

Original language	English (US)
Pages (from-to)	102-106
Number of pages	5
Journal	Journal of CO2 Utilization
Volume	3-4
DOIs	https://doi.org/10.1016/j.jcou.2013.10.002
State	Published - 2013

All Science Journal Classification (ASJC) codes

Chemical Engineering (miscellaneous)
Waste Management and Disposal
Process Chemistry and Technology

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10.1016/j.jcou.2013.10.002

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title = "Bimetallic Fe-Co catalysts for CO2 hydrogenation to higher hydrocarbons",

abstract = "This paper reports on Fe-Co bimetallic catalysts that are active and selective for synthesis of olefin-rich C2+ hydrocarbons from CO2 hydrogenation. The combination of Fe and a small amount of Co led to a dramatic bimetallic promotion of C2+ hydrocarbons synthesis in CO2 hydrogenation on Fe-Co/Al 2O3 catalyst with 15 wt\% total metal loading. The addition of K to Fe-Co/Al2O3 catalyst further improved the formation rate of C2+ hydrocarbons as well as their olefin contents, while it suppressed CH4 formation significantly. Olefin-rich C2+ hydrocarbons was successfully synthesized using K-promoted Fe-Co/Al2O3 catalysts with high K loadings (Co/(Co + Fe) = 0.17 atom atom-1, K/Fe ≥ 0.5 atom atom-1) using CO2 as a carbon source.",

author = "Ratchprapa Satthawong and Naoto Koizumi and Chunshan Song and Pattarapan Prasassarakich",

note = "Funding Information: This research is supported in part by the Pennsylvania State University through Penn State Institutes of Energy and the Environment. The authors also wish to thank the Thailand Research Fund and Graduate School of Chulalongkorn University through the Royal Golden Jubilee Ph.D. Program Scholarship to RS at PSU. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.",

year = "2013",

doi = "10.1016/j.jcou.2013.10.002",

language = "English (US)",

volume = "3-4",

pages = "102--106",

journal = "Journal of CO2 Utilization",

issn = "2212-9820",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Bimetallic Fe-Co catalysts for CO2 hydrogenation to higher hydrocarbons

AU - Satthawong, Ratchprapa

AU - Koizumi, Naoto

AU - Song, Chunshan

AU - Prasassarakich, Pattarapan

N1 - Funding Information: This research is supported in part by the Pennsylvania State University through Penn State Institutes of Energy and the Environment. The authors also wish to thank the Thailand Research Fund and Graduate School of Chulalongkorn University through the Royal Golden Jubilee Ph.D. Program Scholarship to RS at PSU. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.

PY - 2013

Y1 - 2013

N2 - This paper reports on Fe-Co bimetallic catalysts that are active and selective for synthesis of olefin-rich C2+ hydrocarbons from CO2 hydrogenation. The combination of Fe and a small amount of Co led to a dramatic bimetallic promotion of C2+ hydrocarbons synthesis in CO2 hydrogenation on Fe-Co/Al 2O3 catalyst with 15 wt% total metal loading. The addition of K to Fe-Co/Al2O3 catalyst further improved the formation rate of C2+ hydrocarbons as well as their olefin contents, while it suppressed CH4 formation significantly. Olefin-rich C2+ hydrocarbons was successfully synthesized using K-promoted Fe-Co/Al2O3 catalysts with high K loadings (Co/(Co + Fe) = 0.17 atom atom-1, K/Fe ≥ 0.5 atom atom-1) using CO2 as a carbon source.

AB - This paper reports on Fe-Co bimetallic catalysts that are active and selective for synthesis of olefin-rich C2+ hydrocarbons from CO2 hydrogenation. The combination of Fe and a small amount of Co led to a dramatic bimetallic promotion of C2+ hydrocarbons synthesis in CO2 hydrogenation on Fe-Co/Al 2O3 catalyst with 15 wt% total metal loading. The addition of K to Fe-Co/Al2O3 catalyst further improved the formation rate of C2+ hydrocarbons as well as their olefin contents, while it suppressed CH4 formation significantly. Olefin-rich C2+ hydrocarbons was successfully synthesized using K-promoted Fe-Co/Al2O3 catalysts with high K loadings (Co/(Co + Fe) = 0.17 atom atom-1, K/Fe ≥ 0.5 atom atom-1) using CO2 as a carbon source.

UR - https://www.scopus.com/pages/publications/84889099270

UR - https://www.scopus.com/pages/publications/84889099270#tab=citedBy

U2 - 10.1016/j.jcou.2013.10.002

DO - 10.1016/j.jcou.2013.10.002

M3 - Article

AN - SCOPUS:84889099270

SN - 2212-9820

VL - 3-4

SP - 102

EP - 106

JO - Journal of CO2 Utilization

JF - Journal of CO2 Utilization

ER -

Bimetallic Fe-Co catalysts for CO₂ hydrogenation to higher hydrocarbons

Abstract

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