Bis(dialkylphosphinylmethyl)alkylamines as the liquid and membrane extractants of rare earth and trace metal ions

N. Davletshina; R. Cherkasov; A. Garifzyanov; M. Valeeva; S. Koshkin; R. Davletshin; S. Leonteva

doi:10.1080/10426507.2012.740693

Bis(dialkylphosphinylmethyl)alkylamines as the liquid and membrane extractants of rare earth and trace metal ions

N. Davletshina
, R. Cherkasov
, A. Garifzyanov
, M. Valeeva
, S. Koshkin
, R. Davletshin
, S. Leonteva

Huck Institutes of the Life Sciences

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A large number of new lipophilic mono- and bisphosphinylamines were synthesized on the basis of the Kabachnik-Fields reaction and extraction and membrane transport properties of the synthesized compounds toward the rare earth and alkaline metal were studied. Aminophosphonyls demonstrate extracting efficiency and selectivity toward Sc(III), In(III), Y(III), and Ga(III) rare earth elements. The mixture of reactants bis(dialkylphosphinylmethyl)alkylamine, and thio- and dithiophosphoric acid shows selectivity toward lithium ions.

Original language	English (US)
Pages (from-to)	13-14
Number of pages	2
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	188
Issue number	1-3
DOIs	https://doi.org/10.1080/10426507.2012.740693
State	Published - Jan 1 2013

All Science Journal Classification (ASJC) codes

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426507.2012.740693

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abstract = "A large number of new lipophilic mono- and bisphosphinylamines were synthesized on the basis of the Kabachnik-Fields reaction and extraction and membrane transport properties of the synthesized compounds toward the rare earth and alkaline metal were studied. Aminophosphonyls demonstrate extracting efficiency and selectivity toward Sc(III), In(III), Y(III), and Ga(III) rare earth elements. The mixture of reactants bis(dialkylphosphinylmethyl)alkylamine, and thio- and dithiophosphoric acid shows selectivity toward lithium ions.",

author = "N. Davletshina and R. Cherkasov and A. Garifzyanov and M. Valeeva and S. Koshkin and R. Davletshin and S. Leonteva",

note = "Funding Information: Received 25 June 2012; accepted 14 October 2012. This work was carried out under the financial support of the Russian Foundation for Basic research (grant no. 10-03-00580). Address correspondence to Prof. Dr. Rafael Cherkasov, A. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya 29/1, Kazan, Tatarstan 420008, Russian Federation. E-mail: [email protected]",

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T1 - Bis(dialkylphosphinylmethyl)alkylamines as the liquid and membrane extractants of rare earth and trace metal ions

AU - Davletshina, N.

AU - Cherkasov, R.

AU - Garifzyanov, A.

AU - Valeeva, M.

AU - Koshkin, S.

AU - Davletshin, R.

AU - Leonteva, S.

N1 - Funding Information: Received 25 June 2012; accepted 14 October 2012. This work was carried out under the financial support of the Russian Foundation for Basic research (grant no. 10-03-00580). Address correspondence to Prof. Dr. Rafael Cherkasov, A. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya 29/1, Kazan, Tatarstan 420008, Russian Federation. E-mail: [email protected]

PY - 2013/1/1

Y1 - 2013/1/1

N2 - A large number of new lipophilic mono- and bisphosphinylamines were synthesized on the basis of the Kabachnik-Fields reaction and extraction and membrane transport properties of the synthesized compounds toward the rare earth and alkaline metal were studied. Aminophosphonyls demonstrate extracting efficiency and selectivity toward Sc(III), In(III), Y(III), and Ga(III) rare earth elements. The mixture of reactants bis(dialkylphosphinylmethyl)alkylamine, and thio- and dithiophosphoric acid shows selectivity toward lithium ions.

AB - A large number of new lipophilic mono- and bisphosphinylamines were synthesized on the basis of the Kabachnik-Fields reaction and extraction and membrane transport properties of the synthesized compounds toward the rare earth and alkaline metal were studied. Aminophosphonyls demonstrate extracting efficiency and selectivity toward Sc(III), In(III), Y(III), and Ga(III) rare earth elements. The mixture of reactants bis(dialkylphosphinylmethyl)alkylamine, and thio- and dithiophosphoric acid shows selectivity toward lithium ions.

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DO - 10.1080/10426507.2012.740693

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SN - 1042-6507

VL - 188

SP - 13

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JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

IS - 1-3

ER -

Bis(dialkylphosphinylmethyl)alkylamines as the liquid and membrane extractants of rare earth and trace metal ions

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