Breaking the Schulz-Flory barrier: Highly selective transition metal-catalyzed trimerization of ethylene to 1-hexene

S. B. Harkins; S. Murtuza; A. Sen

Breaking the Schulz-Flory barrier: Highly selective transition metal-catalyzed trimerization of ethylene to 1-hexene

S. B. Harkins, S. Murtuza, A. Sen

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

A new two-component catalyst system for the trimerization of ethylene to 1-hexene with high selectivity is presented. This contrasts with typical oligomerization reactions of this type, where a wide range of α-olefins from C₄ to over C₃₀ are observed and the population is described by a Schulz-Flory distribution pattern. GC and ¹H-NMR quantified the products. Reaction results and the nature of the catalyst are discussed. Original is an abstract.

Original language	English (US)
Pages (from-to)	INOR-142
Journal	ACS National Meeting Book of Abstracts
Volume	PART 1
State	Published - Dec 1 1999
Event	Proceedings of the 1999 218th ACS National Meeting - New Oeleans, LA, United States Duration: Aug 22 1999 → Aug 26 1999

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

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title = "Breaking the Schulz-Flory barrier: Highly selective transition metal-catalyzed trimerization of ethylene to 1-hexene",

abstract = "A new two-component catalyst system for the trimerization of ethylene to 1-hexene with high selectivity is presented. This contrasts with typical oligomerization reactions of this type, where a wide range of α-olefins from C4 to over C30 are observed and the population is described by a Schulz-Flory distribution pattern. GC and 1H-NMR quantified the products. Reaction results and the nature of the catalyst are discussed. Original is an abstract.",

author = "Harkins, {S. B.} and S. Murtuza and A. Sen",

year = "1999",

month = dec,

day = "1",

language = "English (US)",

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pages = "INOR--142",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

note = "Proceedings of the 1999 218th ACS National Meeting ; Conference date: 22-08-1999 Through 26-08-1999",

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T1 - Breaking the Schulz-Flory barrier

T2 - Proceedings of the 1999 218th ACS National Meeting

AU - Harkins, S. B.

AU - Murtuza, S.

AU - Sen, A.

PY - 1999/12/1

Y1 - 1999/12/1

N2 - A new two-component catalyst system for the trimerization of ethylene to 1-hexene with high selectivity is presented. This contrasts with typical oligomerization reactions of this type, where a wide range of α-olefins from C4 to over C30 are observed and the population is described by a Schulz-Flory distribution pattern. GC and 1H-NMR quantified the products. Reaction results and the nature of the catalyst are discussed. Original is an abstract.

AB - A new two-component catalyst system for the trimerization of ethylene to 1-hexene with high selectivity is presented. This contrasts with typical oligomerization reactions of this type, where a wide range of α-olefins from C4 to over C30 are observed and the population is described by a Schulz-Flory distribution pattern. GC and 1H-NMR quantified the products. Reaction results and the nature of the catalyst are discussed. Original is an abstract.

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M3 - Comment/debate

AN - SCOPUS:0033367630

SN - 0065-7727

VL - PART 1

SP - INOR-142

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

Y2 - 22 August 1999 through 26 August 1999

ER -

Breaking the Schulz-Flory barrier: Highly selective transition metal-catalyzed trimerization of ethylene to 1-hexene

Abstract

All Science Journal Classification (ASJC) codes

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