Catalysis by Solvated Transition-Metal Cations. 3. Novel Catalytic Transformations of Alkenes by Catlonic Compounds of Molybdenum and Tungsten

Ayusman Sen; Richard R. Thomas

doi:10.1021/om00069a032

Catalysis by Solvated Transition-Metal Cations. 3. Novel Catalytic Transformations of Alkenes by Catlonic Compounds of Molybdenum and Tungsten

Ayusman Sen, Richard R. Thomas

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Abstract

The compounds [M(NO)₂(CH₃CN)₄](BF₄)₂; (2, M = Mo; 3, M = W) were synthesized through reactions of the corresponding metal hexacarbonyls with 2 equiv of NOBF₄ in acetonitrile. These compounds catalyze the polymerization, oligomerization, and rearrangement of olefins.

Original language	English (US)
Pages (from-to)	1251-1254
Number of pages	4
Journal	Organometallics
Volume	1
Issue number	9
DOIs	https://doi.org/10.1021/om00069a032
State	Published - Jan 1 1982

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00069a032

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title = "Catalysis by Solvated Transition-Metal Cations. 3. Novel Catalytic Transformations of Alkenes by Catlonic Compounds of Molybdenum and Tungsten",

abstract = "The compounds [M(NO)2(CH3CN)4](BF4)2; (2, M = Mo; 3, M = W) were synthesized through reactions of the corresponding metal hexacarbonyls with 2 equiv of NOBF4 in acetonitrile. These compounds catalyze the polymerization, oligomerization, and rearrangement of olefins.",

author = "Ayusman Sen and Thomas, {Richard R.}",

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Y1 - 1982/1/1

N2 - The compounds [M(NO)2(CH3CN)4](BF4)2; (2, M = Mo; 3, M = W) were synthesized through reactions of the corresponding metal hexacarbonyls with 2 equiv of NOBF4 in acetonitrile. These compounds catalyze the polymerization, oligomerization, and rearrangement of olefins.

AB - The compounds [M(NO)2(CH3CN)4](BF4)2; (2, M = Mo; 3, M = W) were synthesized through reactions of the corresponding metal hexacarbonyls with 2 equiv of NOBF4 in acetonitrile. These compounds catalyze the polymerization, oligomerization, and rearrangement of olefins.

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Catalysis by Solvated Transition-Metal Cations. 3. Novel Catalytic Transformations of Alkenes by Catlonic Compounds of Molybdenum and Tungsten

Abstract

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