Catalytic dioxygen activation by Co(II) complexes employing a coordinatively versatile ligand scaffold

Savita K. Sharma; Philip S. May; Matthew B. Jones; Sheri Lense; Kenneth I. Hardcastle; Cora E. MacBeth

doi:10.1039/c0cc04671j

Catalytic dioxygen activation by Co(II) complexes employing a coordinatively versatile ligand scaffold

Savita K. Sharma
, Philip S. May
, Matthew B. Jones
, Sheri Lense
, Kenneth I. Hardcastle
, Cora E. MacBeth

School of Science (Behrend)

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The ligand bis(2-isobutyrylamidophenyl)amine has been prepared and used to stabilize both mononuclear and dinuclear cobalt(II) complexes. The nuclearity of the cobalt product is regulated by the deprotonation state of the ligand. Both complexes catalytically oxidize triphenylphosphine to triphenylphosphine oxide in the presence of O₂.

Original language	English (US)
Pages (from-to)	1827-1829
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	6
DOIs	https://doi.org/10.1039/c0cc04671j
State	Published - Jan 27 2011

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c0cc04671j

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abstract = "The ligand bis(2-isobutyrylamidophenyl)amine has been prepared and used to stabilize both mononuclear and dinuclear cobalt(II) complexes. The nuclearity of the cobalt product is regulated by the deprotonation state of the ligand. Both complexes catalytically oxidize triphenylphosphine to triphenylphosphine oxide in the presence of O2.",

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T1 - Catalytic dioxygen activation by Co(II) complexes employing a coordinatively versatile ligand scaffold

AU - Sharma, Savita K.

AU - May, Philip S.

AU - Jones, Matthew B.

AU - Lense, Sheri

AU - Hardcastle, Kenneth I.

AU - MacBeth, Cora E.

PY - 2011/1/27

Y1 - 2011/1/27

N2 - The ligand bis(2-isobutyrylamidophenyl)amine has been prepared and used to stabilize both mononuclear and dinuclear cobalt(II) complexes. The nuclearity of the cobalt product is regulated by the deprotonation state of the ligand. Both complexes catalytically oxidize triphenylphosphine to triphenylphosphine oxide in the presence of O2.

AB - The ligand bis(2-isobutyrylamidophenyl)amine has been prepared and used to stabilize both mononuclear and dinuclear cobalt(II) complexes. The nuclearity of the cobalt product is regulated by the deprotonation state of the ligand. Both complexes catalytically oxidize triphenylphosphine to triphenylphosphine oxide in the presence of O2.

UR - https://www.scopus.com/pages/publications/79251516119

UR - https://www.scopus.com/pages/publications/79251516119#tab=citedBy

U2 - 10.1039/c0cc04671j

DO - 10.1039/c0cc04671j

M3 - Article

AN - SCOPUS:79251516119

SN - 1359-7345

VL - 47

SP - 1827

EP - 1829

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Catalytic dioxygen activation by Co(II) complexes employing a coordinatively versatile ligand scaffold

Abstract

All Science Journal Classification (ASJC) codes

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