TY - JOUR
T1 - Catalytic oxidation of carbon/carbon composite materials in the presence of potassium and calcium acetates
AU - Wu, Xianxian
AU - Radovic, Ljubisa R.
N1 - Funding Information:
This work was supported by the Carbon Research Center at the Energy Institute of the Pennsylvania State University (F. Rusinko, Jr. Director). We thank T. Walker of Honeywell Inc. for providing samples of C/C composites.
PY - 2005
Y1 - 2005
N2 - The catalytic effects of potassium acetate (KAC) and calcium acetate (CaAC) on the oxidation of carbon/carbon composites (C/C composites) used in aircraft brake system have been characterized. Potassium exhibited a very strong catalytic effect on the oxidation of the selected carbon samples, including C/C composite blocks impregnated with aqueous KAC solution and graphite powder physically mixed with KAC powder. The initial amount of catalyst loading and the pre-treatment in inert gas were found to affect its catalytic effectiveness. Impregnated calcium was also a good catalyst for the oxidation of C/C composites, but its effectiveness is much lower than that of potassium and is much less sensitive to catalyst loading amount and pre-treatment. Calcium acetate physically mixed with graphite powder only showed a slight catalytic effect. The experimental results suggested that the interfacial contact between catalyst and carbon is the key factor determining catalytic effectiveness, in agreement with previous studies using porous carbon materials. Due to its unique wetting ability and mobility on the carbon surface, potassium can form and maintain such contact with carbon and is, therefore, more effective in the C-O2 reaction than calcium. The formation and development of such contact, which can also be affected by catalyst loading and pre-treatment process, can explain well the influence of these experimental conditions on the catalytic effect of potassium. The decreasing trend of reactivity with increasing burn-off in calcium-catalyzed oxidation is a result of interfacial contact loss because calcium does not have the necessary mobility to maintain such contact during reaction.
AB - The catalytic effects of potassium acetate (KAC) and calcium acetate (CaAC) on the oxidation of carbon/carbon composites (C/C composites) used in aircraft brake system have been characterized. Potassium exhibited a very strong catalytic effect on the oxidation of the selected carbon samples, including C/C composite blocks impregnated with aqueous KAC solution and graphite powder physically mixed with KAC powder. The initial amount of catalyst loading and the pre-treatment in inert gas were found to affect its catalytic effectiveness. Impregnated calcium was also a good catalyst for the oxidation of C/C composites, but its effectiveness is much lower than that of potassium and is much less sensitive to catalyst loading amount and pre-treatment. Calcium acetate physically mixed with graphite powder only showed a slight catalytic effect. The experimental results suggested that the interfacial contact between catalyst and carbon is the key factor determining catalytic effectiveness, in agreement with previous studies using porous carbon materials. Due to its unique wetting ability and mobility on the carbon surface, potassium can form and maintain such contact with carbon and is, therefore, more effective in the C-O2 reaction than calcium. The formation and development of such contact, which can also be affected by catalyst loading and pre-treatment process, can explain well the influence of these experimental conditions on the catalytic effect of potassium. The decreasing trend of reactivity with increasing burn-off in calcium-catalyzed oxidation is a result of interfacial contact loss because calcium does not have the necessary mobility to maintain such contact during reaction.
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U2 - 10.1016/j.carbon.2004.09.025
DO - 10.1016/j.carbon.2004.09.025
M3 - Article
AN - SCOPUS:9644301118
SN - 0008-6223
VL - 43
SP - 333
EP - 344
JO - Carbon
JF - Carbon
IS - 2
ER -