Catechol-Functionalized Chitosan Synthesis and Selective Extraction of Germanium (IV) from Acidic Solutions

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Abstract

Germanium (Ge) is one of the critical elements that lack an efficient economic recovery process from dilute sources. An improved catechol-based adsorbent, catechol-functionalized chitosan (C-Cat), was synthesized to recover germanium (Ge) from dilute acidic solutions. The adsorbent was also compared with an N-methylglucamine-based commercial adsorbent (Purolite S108) for optimum pH conditions, ion selectivity, adsorption isotherm, adsorption kinetics, and regeneration ability. The newly synthesized C-Cat exhibited higher selectivity against various competing ions than the commercial one (their respective Langmuir capacity was 22.72 and 79.66 mg/g at pH 3) and was more selective for Ge than other adsorbents reported in the literature. Linear free-energy relationships between the distribution coefficients and the metal hydrolysis constants were developed for both C-Cat and S108 at pH 3 and can be used for preliminary prediction of the selectivity of the adsorbents. Adsorptions data followed Langmuir isotherm for both adsorbents, and the kinetics data were well-fitted with pseudo-second-order kinetics. The C-Cat was proven to be completely reusable for multiple cycles after initial re-equilibration.

Original languageEnglish (US)
Pages (from-to)2892-2903
Number of pages12
JournalIndustrial and Engineering Chemistry Research
Volume62
Issue number6
DOIs
StatePublished - Feb 15 2023

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Chemical Engineering
  • Industrial and Manufacturing Engineering

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