catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate

Shaun O. Sommerer; Barry L. Westcott; Alan J. Jircitano; Khalil A. Abboud

doi:10.1107/S0108270196001503

catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate

Shaun O. Sommerer
, Barry L. Westcott
, Alan J. Jircitano
, Khalil A. Abboud

School of Science (Behrend)

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The title complex, [Ag(C₁₁H₈N₂O)]⁺ _n.n(BF₄)^-, contains polymeric [silver(di-2-pyridyl ketone)]⁺_n zigzag chains, counterbalanced by BF^-₄ anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF^-₄ ions also reside on inversion centers (and are disordered). The AgN₂O₂ moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) Å, and N-Ag-O 69.35 (9)^o.

Original language	English (US)
Pages (from-to)	1426-1428
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	6
DOIs	https://doi.org/10.1107/S0108270196001503
State	Published - Jun 15 1996

All Science Journal Classification (ASJC) codes

General Biochemistry, Genetics and Molecular Biology

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@article{8fe25345579f46b7ae8b8ecc55cbf1a6,

title = "catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate",

abstract = "The title complex, [Ag(C11H8N2O)]+ n.n(BF4)-, contains polymeric [silver(di-2-pyridyl ketone)]+n zigzag chains, counterbalanced by BF-4 anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF-4 ions also reside on inversion centers (and are disordered). The AgN2O2 moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) {\AA}, and N-Ag-O 69.35 (9)o.",

author = "Sommerer, \{Shaun O.\} and Westcott, \{Barry L.\} and Jircitano, \{Alan J.\} and Abboud, \{Khalil A.\}",

year = "1996",

month = jun,

day = "15",

doi = "10.1107/S0108270196001503",

language = "English (US)",

volume = "52",

pages = "1426--1428",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate

AU - Sommerer, Shaun O.

AU - Westcott, Barry L.

AU - Jircitano, Alan J.

AU - Abboud, Khalil A.

PY - 1996/6/15

Y1 - 1996/6/15

N2 - The title complex, [Ag(C11H8N2O)]+ n.n(BF4)-, contains polymeric [silver(di-2-pyridyl ketone)]+n zigzag chains, counterbalanced by BF-4 anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF-4 ions also reside on inversion centers (and are disordered). The AgN2O2 moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) Å, and N-Ag-O 69.35 (9)o.

AB - The title complex, [Ag(C11H8N2O)]+ n.n(BF4)-, contains polymeric [silver(di-2-pyridyl ketone)]+n zigzag chains, counterbalanced by BF-4 anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF-4 ions also reside on inversion centers (and are disordered). The AgN2O2 moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) Å, and N-Ag-O 69.35 (9)o.

UR - https://www.scopus.com/pages/publications/0030172564

UR - https://www.scopus.com/pages/publications/0030172564#tab=citedBy

U2 - 10.1107/S0108270196001503

DO - 10.1107/S0108270196001503

M3 - Article

AN - SCOPUS:0030172564

SN - 0108-2701

VL - 52

SP - 1426

EP - 1428

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate

Abstract

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