Chalcogenide-based lithium solid electrolytes processed by the Powder-in-a-tube method

Seth S. Berbano; Malick Y. Fofana; Clive A. Randall; Michael T. Lanagan

doi:10.1016/j.matlet.2014.11.047

Chalcogenide-based lithium solid electrolytes processed by the Powder-in-a-tube method

Seth S. Berbano, Malick Y. Fofana, Clive A. Randall, Michael T. Lanagan

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Solid electrolytes are candidate materials for solid-state batteries and electrochemical capacitors. Viability of a Powder-in-a-tube (PIT) process, most commonly associated with processing of superconductor wires, is shown in sulfide-based lithium solid electrolytes. PIT processing is used to create thin (120 μm) electrolytes sheathed within an aluminum tube. Extrapolated room temperature ionic conductivities reach 10^-3 (Ω cm)^-1 in both rolled PIT and pelletized 0.70Li₂S+0.30P₂S₅ (mol fraction) lithium thiophosphate solid electrolytes which crystallized to form Li₇P₃S₁₁ after heat treatment.

Original language	English (US)
Pages (from-to)	70-72
Number of pages	3
Journal	Materials Letters
Volume	141
DOIs	https://doi.org/10.1016/j.matlet.2014.11.047
State	Published - Feb 15 2015

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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title = "Chalcogenide-based lithium solid electrolytes processed by the Powder-in-a-tube method",

abstract = "Solid electrolytes are candidate materials for solid-state batteries and electrochemical capacitors. Viability of a Powder-in-a-tube (PIT) process, most commonly associated with processing of superconductor wires, is shown in sulfide-based lithium solid electrolytes. PIT processing is used to create thin (120 μm) electrolytes sheathed within an aluminum tube. Extrapolated room temperature ionic conductivities reach 10-3 (Ω cm)-1 in both rolled PIT and pelletized 0.70Li2S+0.30P2S5 (mol fraction) lithium thiophosphate solid electrolytes which crystallized to form Li7P3S11 after heat treatment.",

author = "Berbano, {Seth S.} and Fofana, {Malick Y.} and Randall, {Clive A.} and Lanagan, {Michael T.}",

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AU - Berbano, Seth S.

AU - Fofana, Malick Y.

AU - Randall, Clive A.

AU - Lanagan, Michael T.

PY - 2015/2/15

Y1 - 2015/2/15

N2 - Solid electrolytes are candidate materials for solid-state batteries and electrochemical capacitors. Viability of a Powder-in-a-tube (PIT) process, most commonly associated with processing of superconductor wires, is shown in sulfide-based lithium solid electrolytes. PIT processing is used to create thin (120 μm) electrolytes sheathed within an aluminum tube. Extrapolated room temperature ionic conductivities reach 10-3 (Ω cm)-1 in both rolled PIT and pelletized 0.70Li2S+0.30P2S5 (mol fraction) lithium thiophosphate solid electrolytes which crystallized to form Li7P3S11 after heat treatment.

AB - Solid electrolytes are candidate materials for solid-state batteries and electrochemical capacitors. Viability of a Powder-in-a-tube (PIT) process, most commonly associated with processing of superconductor wires, is shown in sulfide-based lithium solid electrolytes. PIT processing is used to create thin (120 μm) electrolytes sheathed within an aluminum tube. Extrapolated room temperature ionic conductivities reach 10-3 (Ω cm)-1 in both rolled PIT and pelletized 0.70Li2S+0.30P2S5 (mol fraction) lithium thiophosphate solid electrolytes which crystallized to form Li7P3S11 after heat treatment.

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ER -

Chalcogenide-based lithium solid electrolytes processed by the Powder-in-a-tube method

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