TY - JOUR
T1 - Chloridonitrosyl[meso-5,10,15,20-tetrakis(ptolyl)porphyrinato- κ4 N,N′,N″,N‴]osmium(II) tetrahydrofuran tetrasolvate
AU - Chen, Li
AU - Xu, Nan
AU - Powell, Douglas R.
AU - Richter-Addo, George B.
PY - 2011/2
Y1 - 2011/2
N2 - The title compound, [OsCl(NO)(C48H36N 4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.
AB - The title compound, [OsCl(NO)(C48H36N 4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.
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U2 - 10.1107/S1600536811001401
DO - 10.1107/S1600536811001401
M3 - Article
C2 - 21522883
AN - SCOPUS:79751518133
SN - 1600-5368
VL - 67
SP - m224
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 2
ER -