Chloridonitrosyl[meso-5,10,15,20-tetrakis(ptolyl)porphyrinato- κ4 N,N′,N″,N‴]osmium(II) tetrahydrofuran tetrasolvate

Li Chen; Nan Xu; Douglas R. Powell; George B. Richter-Addo

doi:10.1107/S1600536811001401

Chloridonitrosyl[meso-5,10,15,20-tetrakis(ptolyl)porphyrinato- κ⁴ N,N′,N″,N‴]osmium(II) tetrahydrofuran tetrasolvate

Li Chen
, Nan Xu
, Douglas R. Powell
, George B. Richter-Addo

Division of Mathematics & Natural Sciences (Altoona)

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, [OsCl(NO)(C₄₈H₃₆N ₄)]·4C₄H₈O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.

Original language	English (US)
Pages (from-to)	m224
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	2
DOIs	https://doi.org/10.1107/S1600536811001401
State	Published - Feb 2011

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Chloridonitrosyl[meso-5,10,15,20-tetrakis(ptolyl)porphyrinato- κ4 N,N′,N″,N‴]osmium(II) tetrahydrofuran tetrasolvate",

abstract = "The title compound, [OsCl(NO)(C48H36N 4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.",

author = "Li Chen and Nan Xu and Powell, \{Douglas R.\} and Richter-Addo, \{George B.\}",

year = "2011",

month = feb,

doi = "10.1107/S1600536811001401",

language = "English (US)",

volume = "67",

pages = "m224",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - Chloridonitrosyl[meso-5,10,15,20-tetrakis(ptolyl)porphyrinato- κ4 N,N′,N″,N‴]osmium(II) tetrahydrofuran tetrasolvate

AU - Chen, Li

AU - Xu, Nan

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

PY - 2011/2

Y1 - 2011/2

N2 - The title compound, [OsCl(NO)(C48H36N 4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.

AB - The title compound, [OsCl(NO)(C48H36N 4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.

UR - https://www.scopus.com/pages/publications/79751518133

UR - https://www.scopus.com/pages/publications/79751518133#tab=citedBy

U2 - 10.1107/S1600536811001401

DO - 10.1107/S1600536811001401

M3 - Article

C2 - 21522883

AN - SCOPUS:79751518133

SN - 1600-5368

VL - 67

SP - m224

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Chloridonitrosyl[meso-5,10,15,20-tetrakis(ptolyl)porphyrinato- κ⁴ N,N′,N″,N‴]osmium(II) tetrahydrofuran tetrasolvate

Abstract

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