TY - JOUR
T1 - Coating Ni particles to preserve their conductivity during sintering in oxidizing atmospheres
AU - Sohrabi Baba Heidary, Damoon
AU - Randall, Clive A.
N1 - Funding Information:
This material is based upon work supported by the National Science Foundation I/UCRC, as part of the Center for Dielectric and Piezoelectrics ( CDP ) under Grant Nos. IIP-1361503 and 1361571 . We thank the members for many useful conversations, especially from Dr. Larry Mann of Shoei Chemical. In addition, the authors like to acknowledge Dr. Trevor Clark and Dr. Bernd Kabius in Material Characterization Laboratory at the Pennsylvania State University for their consultations.
Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2016/11/15
Y1 - 2016/11/15
N2 - In this study, a new Ni electrode was introduced which was able to preserve its electrical conductivity during sintering in oxidizing atmosphere. The Ni electrode was manufactured from Ni nanoparticles, which were coated by Li salts, namely Li2CO3, LiOH, and LiF, with an innovative coating method. The coating process is schematically shown in the graphical abstract. After the confirmation of a successful coating on Ni particles by SEM (Scanning Electron Microcopy) imaging, the Ni particles with Li2CO3 coating demonstrated the greatest preservation in conductivity among the other salts. Thus they were selected for further investigation; the effect of Li2CO3 percentage, sintering program, and pO2 on electrode resistance were systematically studied. The results suggest that the coating can reduce the resistance by five orders of magnitude at oxidizing atmosphere (e.g. pO2 = 2 × 10−4 atm). The reduced resistances were as low as 1 Ω, suitable to be used as an electrode. SEM and FIB (Focused Ion Beam) cross section imaging were used to document the Ni oxidation, the sintering process of Ni particles, and the Li2CO3 decomposition. Finally, two mechanisms were speculated to be the reasons of the conductivity conservation and the importance of this invention in the reducing of oxygen vacancies in electroceramic devices was discussed.
AB - In this study, a new Ni electrode was introduced which was able to preserve its electrical conductivity during sintering in oxidizing atmosphere. The Ni electrode was manufactured from Ni nanoparticles, which were coated by Li salts, namely Li2CO3, LiOH, and LiF, with an innovative coating method. The coating process is schematically shown in the graphical abstract. After the confirmation of a successful coating on Ni particles by SEM (Scanning Electron Microcopy) imaging, the Ni particles with Li2CO3 coating demonstrated the greatest preservation in conductivity among the other salts. Thus they were selected for further investigation; the effect of Li2CO3 percentage, sintering program, and pO2 on electrode resistance were systematically studied. The results suggest that the coating can reduce the resistance by five orders of magnitude at oxidizing atmosphere (e.g. pO2 = 2 × 10−4 atm). The reduced resistances were as low as 1 Ω, suitable to be used as an electrode. SEM and FIB (Focused Ion Beam) cross section imaging were used to document the Ni oxidation, the sintering process of Ni particles, and the Li2CO3 decomposition. Finally, two mechanisms were speculated to be the reasons of the conductivity conservation and the importance of this invention in the reducing of oxygen vacancies in electroceramic devices was discussed.
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U2 - 10.1016/j.cej.2016.06.130
DO - 10.1016/j.cej.2016.06.130
M3 - Article
AN - SCOPUS:84990026566
SN - 1385-8947
VL - 304
SP - 1009
EP - 1019
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
ER -