Cobalt porphyrin-catalyzed alkane oxidations using dioxygen as oxidant

Hui Tang; Chengyu Shen; Minren Lin; Ayusman Sen

doi:10.1016/S0020-1693(99)00572-1

Cobalt porphyrin-catalyzed alkane oxidations using dioxygen as oxidant

Hui Tang, Chengyu Shen, Minren Lin, Ayusman Sen

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

In a mixture of trifluoroacetic acid and water, cobalt(II) porphyrin complexes catalyze the oxidation of alkanes by dioxygen. Carbon monoxide is required as a coreductant for the oxidations to proceed. While the turnover rates are slow, the system displays unusual selectivity in that primary C-H bonds are more reactive than the weaker secondary C-H bonds or C-H bonds α to an alcohol functionality. (C) 2000 Elsevier Science S.A.

Original language	English (US)
Pages (from-to)	1109-1111
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	300-302
DOIs	https://doi.org/10.1016/S0020-1693(99)00572-1
State	Published - Apr 30 2000

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(99)00572-1

Cite this

@article{0d4cb6f25e5445aa87ec91f9467975c2,

title = "Cobalt porphyrin-catalyzed alkane oxidations using dioxygen as oxidant",

abstract = "In a mixture of trifluoroacetic acid and water, cobalt(II) porphyrin complexes catalyze the oxidation of alkanes by dioxygen. Carbon monoxide is required as a coreductant for the oxidations to proceed. While the turnover rates are slow, the system displays unusual selectivity in that primary C-H bonds are more reactive than the weaker secondary C-H bonds or C-H bonds α to an alcohol functionality. (C) 2000 Elsevier Science S.A.",

author = "Hui Tang and Chengyu Shen and Minren Lin and Ayusman Sen",

note = "Funding Information: This research was funded by the National Science Foundation. ",

year = "2000",

month = apr,

day = "30",

doi = "10.1016/S0020-1693(99)00572-1",

language = "English (US)",

volume = "300-302",

pages = "1109--1111",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Cobalt porphyrin-catalyzed alkane oxidations using dioxygen as oxidant

AU - Tang, Hui

AU - Shen, Chengyu

AU - Lin, Minren

AU - Sen, Ayusman

N1 - Funding Information: This research was funded by the National Science Foundation.

PY - 2000/4/30

Y1 - 2000/4/30

N2 - In a mixture of trifluoroacetic acid and water, cobalt(II) porphyrin complexes catalyze the oxidation of alkanes by dioxygen. Carbon monoxide is required as a coreductant for the oxidations to proceed. While the turnover rates are slow, the system displays unusual selectivity in that primary C-H bonds are more reactive than the weaker secondary C-H bonds or C-H bonds α to an alcohol functionality. (C) 2000 Elsevier Science S.A.

AB - In a mixture of trifluoroacetic acid and water, cobalt(II) porphyrin complexes catalyze the oxidation of alkanes by dioxygen. Carbon monoxide is required as a coreductant for the oxidations to proceed. While the turnover rates are slow, the system displays unusual selectivity in that primary C-H bonds are more reactive than the weaker secondary C-H bonds or C-H bonds α to an alcohol functionality. (C) 2000 Elsevier Science S.A.

UR - http://www.scopus.com/inward/record.url?scp=17644432044&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=17644432044&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(99)00572-1

DO - 10.1016/S0020-1693(99)00572-1

M3 - Article

AN - SCOPUS:17644432044

SN - 0020-1693

VL - 300-302

SP - 1109

EP - 1111

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Cobalt porphyrin-catalyzed alkane oxidations using dioxygen as oxidant

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this