Coherent raman spectroscopy of HCN complexes

G. A. Hopkins; M. Maroncelli; J. W. Nibler; T. R. Dyke

doi:10.1016/0009-2614(85)85063-6

Coherent raman spectroscopy of HCN complexes

G. A. Hopkins, M. Maroncelli, J. W. Nibler, T. R. Dyke

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Abstract

Photoacoustic Raman spectroscopy (PARS) is shown to be a sensitive technique for obtaining Raman spectra of hydrogen-bonded complexes in the gas phase. Coherent anti-Stokes Raman spectroscopy (CARS) provides analogous spectra in supersonic expansions. The effective resolution is higher in the latter case due to the cooling and collision-free conditions in the jet. The ability to "tune" complex size by changing expansion conditions is demonstrated in the case of HCN.

Original language	English (US)
Pages (from-to)	97-102
Number of pages	6
Journal	Chemical Physics Letters
Volume	114
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(85)85063-6
State	Published - Feb 15 1985

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(85)85063-6

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title = "Coherent raman spectroscopy of HCN complexes",

abstract = "Photoacoustic Raman spectroscopy (PARS) is shown to be a sensitive technique for obtaining Raman spectra of hydrogen-bonded complexes in the gas phase. Coherent anti-Stokes Raman spectroscopy (CARS) provides analogous spectra in supersonic expansions. The effective resolution is higher in the latter case due to the cooling and collision-free conditions in the jet. The ability to {"}tune{"} complex size by changing expansion conditions is demonstrated in the case of HCN.",

author = "Hopkins, {G. A.} and M. Maroncelli and Nibler, {J. W.} and Dyke, {T. R.}",

note = "Funding Information: This research has been supported by the AFOSR and the NSF_ The authors thank Drs. J. Barrett and T. Lundeen for advice and assistance m constructing the PARS cell The pulsed nozzle and drivmg circuitry were based on designs by Dr. H. Selzle and JWN wishes to thank hrm and Professor E. S&lag for their hospitality during a sabbatical at the Technical University of Munich. JWN is also grateful to the Alexander von Humboldt Stiftung for a Senior Scientist Award durmg this period.",

year = "1985",

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doi = "10.1016/0009-2614(85)85063-6",

language = "English (US)",

volume = "114",

pages = "97--102",

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TY - JOUR

T1 - Coherent raman spectroscopy of HCN complexes

AU - Hopkins, G. A.

AU - Maroncelli, M.

AU - Nibler, J. W.

AU - Dyke, T. R.

N1 - Funding Information: This research has been supported by the AFOSR and the NSF_ The authors thank Drs. J. Barrett and T. Lundeen for advice and assistance m constructing the PARS cell The pulsed nozzle and drivmg circuitry were based on designs by Dr. H. Selzle and JWN wishes to thank hrm and Professor E. S&lag for their hospitality during a sabbatical at the Technical University of Munich. JWN is also grateful to the Alexander von Humboldt Stiftung for a Senior Scientist Award durmg this period.

PY - 1985/2/15

Y1 - 1985/2/15

N2 - Photoacoustic Raman spectroscopy (PARS) is shown to be a sensitive technique for obtaining Raman spectra of hydrogen-bonded complexes in the gas phase. Coherent anti-Stokes Raman spectroscopy (CARS) provides analogous spectra in supersonic expansions. The effective resolution is higher in the latter case due to the cooling and collision-free conditions in the jet. The ability to "tune" complex size by changing expansion conditions is demonstrated in the case of HCN.

AB - Photoacoustic Raman spectroscopy (PARS) is shown to be a sensitive technique for obtaining Raman spectra of hydrogen-bonded complexes in the gas phase. Coherent anti-Stokes Raman spectroscopy (CARS) provides analogous spectra in supersonic expansions. The effective resolution is higher in the latter case due to the cooling and collision-free conditions in the jet. The ability to "tune" complex size by changing expansion conditions is demonstrated in the case of HCN.

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SP - 97

EP - 102

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

Coherent raman spectroscopy of HCN complexes

Abstract

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