Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents

J. N. Spencer; J. E. Mihalick; T. J. Nicholson; P. A. Cortina; J. L. Rinehimer; J. E. Smith; Xiaoming Ke; Qing He; S. E. Daniels; Shaym Puppala; James L. Ealy; L. J. Fenton; William J. Nicholson; Ian M. Paul; Claude H. Yoder

doi:10.1021/j100142a040

Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents

J. N. Spencer, J. E. Mihalick, T. J. Nicholson, P. A. Cortina, J. L. Rinehimer, J. E. Smith, Xiaoming Ke, Qing He, S. E. Daniels, Shaym Puppala, James L. Ealy, L. J. Fenton, William J. Nicholson, Ian M. Paul, Claude H. Yoder

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17 Scopus citations

Abstract

Equilibrium constants and enthalpies of host-guest complexation have been determined by calorimetry for cyclic and acyclic polyether hosts with a variety of guests and solvents. The thermodynamic parameters for complexation of group I cation guests by crown ethers in water solvent may be correlated to the hydration enthalpy and relative sizes of cation and ether. The macrocyclic effect is observed for cation-ether systems in water solvent but not for the complexation of malononitrile by ethers in nonpolar aromatic or alcohol solvent.

Original language	English (US)
Pages (from-to)	10509-10512
Number of pages	4
Journal	Journal of physical chemistry
Volume	97
Issue number	40
DOIs	https://doi.org/10.1021/j100142a040
State	Published - 1993

All Science Journal Classification (ASJC) codes

General Engineering
Physical and Theoretical Chemistry

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10.1021/j100142a040

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Spencer, J. N., Mihalick, J. E., Nicholson, T. J., Cortina, P. A., Rinehimer, J. L., Smith, J. E., Ke, X., He, Q., Daniels, S. E., Puppala, S., Ealy, J. L., Fenton, L. J., Nicholson, W. J., Paul, I. M., & Yoder, C. H. (1993). Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents. Journal of physical chemistry, 97(40), 10509-10512. https://doi.org/10.1021/j100142a040

@article{5d8a729672164edc95ea882c6daf2e9a,

title = "Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents",

abstract = "Equilibrium constants and enthalpies of host-guest complexation have been determined by calorimetry for cyclic and acyclic polyether hosts with a variety of guests and solvents. The thermodynamic parameters for complexation of group I cation guests by crown ethers in water solvent may be correlated to the hydration enthalpy and relative sizes of cation and ether. The macrocyclic effect is observed for cation-ether systems in water solvent but not for the complexation of malononitrile by ethers in nonpolar aromatic or alcohol solvent.",

author = "Spencer, {J. N.} and Mihalick, {J. E.} and Nicholson, {T. J.} and Cortina, {P. A.} and Rinehimer, {J. L.} and Smith, {J. E.} and Xiaoming Ke and Qing He and Daniels, {S. E.} and Shaym Puppala and Ealy, {James L.} and Fenton, {L. J.} and Nicholson, {William J.} and Paul, {Ian M.} and Yoder, {Claude H.}",

year = "1993",

doi = "10.1021/j100142a040",

language = "English (US)",

volume = "97",

pages = "10509--10512",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "40",

}

Spencer, JN, Mihalick, JE, Nicholson, TJ, Cortina, PA, Rinehimer, JL, Smith, JE, Ke, X, He, Q, Daniels, SE, Puppala, S, Ealy, JL, Fenton, LJ, Nicholson, WJ, Paul, IM & Yoder, CH 1993, 'Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents', Journal of physical chemistry, vol. 97, no. 40, pp. 10509-10512. https://doi.org/10.1021/j100142a040

TY - JOUR

T1 - Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents

AU - Spencer, J. N.

AU - Mihalick, J. E.

AU - Nicholson, T. J.

AU - Cortina, P. A.

AU - Rinehimer, J. L.

AU - Smith, J. E.

AU - Ke, Xiaoming

AU - He, Qing

AU - Daniels, S. E.

AU - Puppala, Shaym

AU - Ealy, James L.

AU - Fenton, L. J.

AU - Nicholson, William J.

AU - Paul, Ian M.

AU - Yoder, Claude H.

PY - 1993

Y1 - 1993

N2 - Equilibrium constants and enthalpies of host-guest complexation have been determined by calorimetry for cyclic and acyclic polyether hosts with a variety of guests and solvents. The thermodynamic parameters for complexation of group I cation guests by crown ethers in water solvent may be correlated to the hydration enthalpy and relative sizes of cation and ether. The macrocyclic effect is observed for cation-ether systems in water solvent but not for the complexation of malononitrile by ethers in nonpolar aromatic or alcohol solvent.

AB - Equilibrium constants and enthalpies of host-guest complexation have been determined by calorimetry for cyclic and acyclic polyether hosts with a variety of guests and solvents. The thermodynamic parameters for complexation of group I cation guests by crown ethers in water solvent may be correlated to the hydration enthalpy and relative sizes of cation and ether. The macrocyclic effect is observed for cation-ether systems in water solvent but not for the complexation of malononitrile by ethers in nonpolar aromatic or alcohol solvent.

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UR - http://www.scopus.com/inward/citedby.url?scp=0000721675&partnerID=8YFLogxK

U2 - 10.1021/j100142a040

DO - 10.1021/j100142a040

M3 - Article

AN - SCOPUS:0000721675

SN - 0022-3654

VL - 97

SP - 10509

EP - 10512

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 40

ER -

Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents

Abstract

All Science Journal Classification (ASJC) codes

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