Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

Mark Maroncelli; Graham R. Fleming

doi:10.1063/1.455210

Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

Mark Maroncelli, Graham R. Fleming

Research output: Contribution to journal › Review article › peer-review

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Abstract

The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.

Original language	English (US)
Pages (from-to)	875-881
Number of pages	7
Journal	The Journal of chemical physics
Volume	89
Issue number	2
DOIs	https://doi.org/10.1063/1.455210
State	Published - 1988

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.455210

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title = "Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics",

abstract = "The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.",

author = "Mark Maroncelli and Fleming, {Graham R.}",

year = "1988",

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T1 - Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

AU - Maroncelli, Mark

AU - Fleming, Graham R.

PY - 1988

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N2 - The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.

AB - The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.

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DO - 10.1063/1.455210

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AN - SCOPUS:0001222764

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JO - The Journal of chemical physics

JF - The Journal of chemical physics

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ER -

Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

Abstract

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