Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

Mark Maroncelli; Graham R. Fleming

doi:10.1063/1.455210

Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

Mark Maroncelli
, Graham R. Fleming

Research output: Contribution to journal › Review article › peer-review

120 Scopus citations

Abstract

The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.

Original language	English (US)
Pages (from-to)	875-881
Number of pages	7
Journal	The Journal of chemical physics
Volume	89
Issue number	2
DOIs	https://doi.org/10.1063/1.455210
State	Published - 1988

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.455210

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@article{45e4c28c174a4049a07808eb39f82d84,

title = "Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics",

abstract = "The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.",

author = "Mark Maroncelli and Fleming, \{Graham R.\}",

year = "1988",

doi = "10.1063/1.455210",

language = "English (US)",

volume = "89",

pages = "875--881",

journal = "The Journal of chemical physics",

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publisher = "American Institute of Physics",

number = "2",

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T1 - Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

AU - Maroncelli, Mark

AU - Fleming, Graham R.

PY - 1988

Y1 - 1988

N2 - The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.

AB - The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.

UR - https://www.scopus.com/pages/publications/0001222764

UR - https://www.scopus.com/pages/publications/0001222764#tab=citedBy

U2 - 10.1063/1.455210

DO - 10.1063/1.455210

M3 - Review article

AN - SCOPUS:0001222764

SN - 0021-9606

VL - 89

SP - 875

EP - 881

JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 2

ER -

Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

Abstract

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