Complete set of elastic, dielectric, and piezoelectric constants of [011]C poled rhombohedral Pb(In0.5Nb0.5)O 3-Pb(Mg1/3Nb2/3)O3-PbTiO 3:Mn single crystals

Xiaoqing Huo; Shujun Zhang; Gang Liu; Rui Zhang; Jun Luo; Raffi Sahul; Wenwu Cao; Thomas R. Shrout

doi:10.1063/1.4792661

Complete set of elastic, dielectric, and piezoelectric constants of [011]_C poled rhombohedral Pb(In_0.5Nb_0.5)O ₃-Pb(Mg_1/3Nb_2/3)O₃-PbTiO ₃:Mn single crystals

Xiaoqing Huo
, Shujun Zhang
, Gang Liu
, Rui Zhang
, Jun Luo
, Raffi Sahul
, Wenwu Cao
, Thomas R. Shrout

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

Mn modified rhombohedral Pb(In_0.5Nb_0.5)O ₃-Pb(Mg_1/3Nb_2/3)O₃-PbTiO ₃ (PIN-PMN-PT:Mn) single crystals poled along [011]_C crystallographic direction exhibit a "2R" engineered domain configuration, with macroscopic mm2 symmetry. The complete sets of material constants were determined using combined resonance and ultrasonic methods, and compared to [001]_C poled PIN-PMN-PT:Mn crystals. The thickness shear piezoelectric coefficient d₁₅ and electromechanical coupling factor k₁₅ were found to be on the order of ∼3000 pC/N and 0.92, respectively, with longitudinal piezoelectric coefficient d₃₃ and coupling factor k₃₃ being on the order of ∼1050 pC/N and 0.90. Of particular importance is that PIN-PMN-PT:Mn single crystals exhibited high mechanical quality factor Q₃₃ ∼ 1000, comparable to "hard" PZT8 ceramics, which can also be confirmed by the low extrinsic contribution, being ≤2% from the Rayleigh analysis.

Original language	English (US)
Article number	074106
Journal	Journal of Applied Physics
Volume	113
Issue number	7
DOIs	https://doi.org/10.1063/1.4792661
State	Published - Feb 21 2013

All Science Journal Classification (ASJC) codes

Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Physics and Astronomy (miscellaneous)
General Physics and Astronomy

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10.1063/1.4792661

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@article{74bb3609cfed49799d0fb1234c07e574,

title = "Complete set of elastic, dielectric, and piezoelectric constants of [011]C poled rhombohedral Pb(In0.5Nb0.5)O 3-Pb(Mg1/3Nb2/3)O3-PbTiO 3:Mn single crystals",

abstract = "Mn modified rhombohedral Pb(In0.5Nb0.5)O 3-Pb(Mg1/3Nb2/3)O3-PbTiO 3 (PIN-PMN-PT:Mn) single crystals poled along [011]C crystallographic direction exhibit a {"}2R{"} engineered domain configuration, with macroscopic mm2 symmetry. The complete sets of material constants were determined using combined resonance and ultrasonic methods, and compared to [001]C poled PIN-PMN-PT:Mn crystals. The thickness shear piezoelectric coefficient d15 and electromechanical coupling factor k15 were found to be on the order of ∼3000 pC/N and 0.92, respectively, with longitudinal piezoelectric coefficient d33 and coupling factor k33 being on the order of ∼1050 pC/N and 0.90. Of particular importance is that PIN-PMN-PT:Mn single crystals exhibited high mechanical quality factor Q33 ∼ 1000, comparable to {"}hard{"} PZT8 ceramics, which can also be confirmed by the low extrinsic contribution, being ≤2\% from the Rayleigh analysis.",

author = "Xiaoqing Huo and Shujun Zhang and Gang Liu and Rui Zhang and Jun Luo and Raffi Sahul and Wenwu Cao and Shrout, \{Thomas R.\}",

note = "Funding Information: This work was supported by the ONR and NIH under Grant No. 2P41EB002182-15A1.O. The authors from HIT thank the support from National Key Basic Research Program of China under Grant No. 2013CB632900, and the author (X. Q. Huo) wants to thank the support from China Scholarship Council.",

year = "2013",

month = feb,

day = "21",

doi = "10.1063/1.4792661",

language = "English (US)",

volume = "113",

journal = "Journal of Applied Physics",

issn = "0021-8979",

publisher = "American Institute of Physics",

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TY - JOUR

T1 - Complete set of elastic, dielectric, and piezoelectric constants of [011]C poled rhombohedral Pb(In0.5Nb0.5)O 3-Pb(Mg1/3Nb2/3)O3-PbTiO 3:Mn single crystals

AU - Huo, Xiaoqing

AU - Zhang, Shujun

AU - Liu, Gang

AU - Zhang, Rui

AU - Luo, Jun

AU - Sahul, Raffi

AU - Cao, Wenwu

AU - Shrout, Thomas R.

N1 - Funding Information: This work was supported by the ONR and NIH under Grant No. 2P41EB002182-15A1.O. The authors from HIT thank the support from National Key Basic Research Program of China under Grant No. 2013CB632900, and the author (X. Q. Huo) wants to thank the support from China Scholarship Council.

PY - 2013/2/21

Y1 - 2013/2/21

N2 - Mn modified rhombohedral Pb(In0.5Nb0.5)O 3-Pb(Mg1/3Nb2/3)O3-PbTiO 3 (PIN-PMN-PT:Mn) single crystals poled along [011]C crystallographic direction exhibit a "2R" engineered domain configuration, with macroscopic mm2 symmetry. The complete sets of material constants were determined using combined resonance and ultrasonic methods, and compared to [001]C poled PIN-PMN-PT:Mn crystals. The thickness shear piezoelectric coefficient d15 and electromechanical coupling factor k15 were found to be on the order of ∼3000 pC/N and 0.92, respectively, with longitudinal piezoelectric coefficient d33 and coupling factor k33 being on the order of ∼1050 pC/N and 0.90. Of particular importance is that PIN-PMN-PT:Mn single crystals exhibited high mechanical quality factor Q33 ∼ 1000, comparable to "hard" PZT8 ceramics, which can also be confirmed by the low extrinsic contribution, being ≤2% from the Rayleigh analysis.

AB - Mn modified rhombohedral Pb(In0.5Nb0.5)O 3-Pb(Mg1/3Nb2/3)O3-PbTiO 3 (PIN-PMN-PT:Mn) single crystals poled along [011]C crystallographic direction exhibit a "2R" engineered domain configuration, with macroscopic mm2 symmetry. The complete sets of material constants were determined using combined resonance and ultrasonic methods, and compared to [001]C poled PIN-PMN-PT:Mn crystals. The thickness shear piezoelectric coefficient d15 and electromechanical coupling factor k15 were found to be on the order of ∼3000 pC/N and 0.92, respectively, with longitudinal piezoelectric coefficient d33 and coupling factor k33 being on the order of ∼1050 pC/N and 0.90. Of particular importance is that PIN-PMN-PT:Mn single crystals exhibited high mechanical quality factor Q33 ∼ 1000, comparable to "hard" PZT8 ceramics, which can also be confirmed by the low extrinsic contribution, being ≤2% from the Rayleigh analysis.

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Complete set of elastic, dielectric, and piezoelectric constants of [011]_C poled rhombohedral Pb(In_0.5Nb_0.5)O ₃-Pb(Mg_1/3Nb_2/3)O₃-PbTiO ₃:Mn single crystals

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