Complete set of material constants of Pb (In1/2Nb1/2) O3 -Pb (Mg1/3 Nb2/3) O3 - PbTiO3 single crystal with morphotropic phase boundary composition

Xiaozhou Liu; Shujun Zhang; Jun Luo; Thomas R. Shrout; Wenwu Cao

doi:10.1063/1.3243169

Complete set of material constants of Pb (In_1/2Nb_1/2) O₃ -Pb (Mg_1/3 Nb_2/3) O₃ - PbTiO₃ single crystal with morphotropic phase boundary composition

Xiaozhou Liu, Shujun Zhang, Jun Luo, Thomas R. Shrout, Wenwu Cao

Research output: Contribution to journal › Article › peer-review

114 Scopus citations

Abstract

Using combined resonance and ultrasonic methods, a full set of material constants has been measured for morphotropic phase boundary (MPB) composition xPb (In_1/2 Nb_1/2) O₃ - (1-x-y) Pb (Mg _1/3 Nb_2/3) O₃ -y PbTiO₃ (PIN-PMN-PT) single crystals poled along [001] _c. Compared with the MPB composition (1-x) Pb (Mg_1/3 Nb_2/3) O₃ -x PbTiO₃ (PMN-PT) single crystals, the PIN-PMN-PT single crystals have smaller anisotropy, higher Curie temperature (T_c ≈197 °C), and higher rhombohedral to tetragonal phase transition temperature (TR-T ≈96 °C). The electromechanical properties obtained here are the best found so far for this ternary system with d₃₃ ≈2742 pC/N, d₃₁ ≈-1337 pC/N, k₃₃ ≈95%, and k₃₁ ≈65%.

Original language	English (US)
Article number	074112
Journal	Journal of Applied Physics
Volume	106
Issue number	7
DOIs	https://doi.org/10.1063/1.3243169
State	Published - 2009

All Science Journal Classification (ASJC) codes

General Physics and Astronomy

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10.1063/1.3243169

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@article{4ef32b41ee954002a721fc55971c179c,

title = "Complete set of material constants of Pb (In1/2Nb1/2) O3 -Pb (Mg1/3 Nb2/3) O3 - PbTiO3 single crystal with morphotropic phase boundary composition",

abstract = "Using combined resonance and ultrasonic methods, a full set of material constants has been measured for morphotropic phase boundary (MPB) composition xPb (In1/2 Nb1/2) O3 - (1-x-y) Pb (Mg 1/3 Nb2/3) O3 -y PbTiO3 (PIN-PMN-PT) single crystals poled along [001] c. Compared with the MPB composition (1-x) Pb (Mg1/3 Nb2/3) O3 -x PbTiO3 (PMN-PT) single crystals, the PIN-PMN-PT single crystals have smaller anisotropy, higher Curie temperature (Tc ≈197 °C), and higher rhombohedral to tetragonal phase transition temperature (TR-T ≈96 °C). The electromechanical properties obtained here are the best found so far for this ternary system with d33 ≈2742 pC/N, d31 ≈-1337 pC/N, k33 ≈95%, and k31 ≈65%.",

author = "Xiaozhou Liu and Shujun Zhang and Jun Luo and Shrout, {Thomas R.} and Wenwu Cao",

note = "Funding Information: This research was supported by the NIH under Grant No. P41-EB21820 and ONR under Grant No. N00014-09-01-0456 and N00014-07-C-0858.",

year = "2009",

doi = "10.1063/1.3243169",

language = "English (US)",

volume = "106",

journal = "Journal of Applied Physics",

issn = "0021-8979",

publisher = "American Institute of Physics",

number = "7",

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T1 - Complete set of material constants of Pb (In1/2Nb1/2) O3 -Pb (Mg1/3 Nb2/3) O3 - PbTiO3 single crystal with morphotropic phase boundary composition

AU - Liu, Xiaozhou

AU - Zhang, Shujun

AU - Luo, Jun

AU - Shrout, Thomas R.

AU - Cao, Wenwu

N1 - Funding Information: This research was supported by the NIH under Grant No. P41-EB21820 and ONR under Grant No. N00014-09-01-0456 and N00014-07-C-0858.

PY - 2009

Y1 - 2009

N2 - Using combined resonance and ultrasonic methods, a full set of material constants has been measured for morphotropic phase boundary (MPB) composition xPb (In1/2 Nb1/2) O3 - (1-x-y) Pb (Mg 1/3 Nb2/3) O3 -y PbTiO3 (PIN-PMN-PT) single crystals poled along [001] c. Compared with the MPB composition (1-x) Pb (Mg1/3 Nb2/3) O3 -x PbTiO3 (PMN-PT) single crystals, the PIN-PMN-PT single crystals have smaller anisotropy, higher Curie temperature (Tc ≈197 °C), and higher rhombohedral to tetragonal phase transition temperature (TR-T ≈96 °C). The electromechanical properties obtained here are the best found so far for this ternary system with d33 ≈2742 pC/N, d31 ≈-1337 pC/N, k33 ≈95%, and k31 ≈65%.

AB - Using combined resonance and ultrasonic methods, a full set of material constants has been measured for morphotropic phase boundary (MPB) composition xPb (In1/2 Nb1/2) O3 - (1-x-y) Pb (Mg 1/3 Nb2/3) O3 -y PbTiO3 (PIN-PMN-PT) single crystals poled along [001] c. Compared with the MPB composition (1-x) Pb (Mg1/3 Nb2/3) O3 -x PbTiO3 (PMN-PT) single crystals, the PIN-PMN-PT single crystals have smaller anisotropy, higher Curie temperature (Tc ≈197 °C), and higher rhombohedral to tetragonal phase transition temperature (TR-T ≈96 °C). The electromechanical properties obtained here are the best found so far for this ternary system with d33 ≈2742 pC/N, d31 ≈-1337 pC/N, k33 ≈95%, and k31 ≈65%.

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Complete set of material constants of Pb (In_1/2Nb_1/2) O₃ -Pb (Mg_1/3 Nb_2/3) O₃ - PbTiO₃ single crystal with morphotropic phase boundary composition

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