Conformational Analysis of Poly(dihalophosphazenes)

H. R. Allcock; R. W. Allen; J. J. Meister

doi:10.1021/ma60054a014

Conformational Analysis of Poly(dihalophosphazenes)

H. R. Allcock, R. W. Allen, J. J. Meister

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The poly(dihalophosphazenes), (NPF₂)_n, (NPCl₂)_n, and (NPBr₂)_n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.

Original language	English (US)
Pages (from-to)	950-955
Number of pages	6
Journal	Macromolecules
Volume	9
Issue number	6
DOIs	https://doi.org/10.1021/ma60054a014
State	Published - Nov 1 1976

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma60054a014

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title = "Conformational Analysis of Poly(dihalophosphazenes)",

abstract = "The poly(dihalophosphazenes), (NPF2)n, (NPCl2)n, and (NPBr2)n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.",

author = "Allcock, {H. R.} and Allen, {R. W.} and Meister, {J. J.}",

year = "1976",

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AU - Allen, R. W.

AU - Meister, J. J.

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N2 - The poly(dihalophosphazenes), (NPF2)n, (NPCl2)n, and (NPBr2)n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.

AB - The poly(dihalophosphazenes), (NPF2)n, (NPCl2)n, and (NPBr2)n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.

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Conformational Analysis of Poly(dihalophosphazenes)

Abstract

All Science Journal Classification (ASJC) codes

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