Conformational Analysis of Poly(dihalophosphazenes)

H. R. Allcock; R. W. Allen; J. J. Meister

doi:10.1021/ma60054a014

Conformational Analysis of Poly(dihalophosphazenes)

H. R. Allcock
, R. W. Allen
, J. J. Meister

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The poly(dihalophosphazenes), (NPF₂)_n, (NPCl₂)_n, and (NPBr₂)_n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.

Original language	English (US)
Pages (from-to)	950-955
Number of pages	6
Journal	Macromolecules
Volume	9
Issue number	6
DOIs	https://doi.org/10.1021/ma60054a014
State	Published - Nov 1 1976

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1021/ma60054a014

Cite this

@article{764fb634c4ff4651a181aa7a26559495,

title = "Conformational Analysis of Poly(dihalophosphazenes)",

abstract = "The poly(dihalophosphazenes), (NPF2)n, (NPCl2)n, and (NPBr2)n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.",

author = "Allcock, \{H. R.\} and Allen, \{R. W.\} and Meister, \{J. J.\}",

year = "1976",

month = nov,

day = "1",

doi = "10.1021/ma60054a014",

language = "English (US)",

volume = "9",

pages = "950--955",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Conformational Analysis of Poly(dihalophosphazenes)

AU - Allcock, H. R.

AU - Allen, R. W.

AU - Meister, J. J.

PY - 1976/11/1

Y1 - 1976/11/1

N2 - The poly(dihalophosphazenes), (NPF2)n, (NPCl2)n, and (NPBr2)n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.

AB - The poly(dihalophosphazenes), (NPF2)n, (NPCl2)n, and (NPBr2)n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.

UR - https://www.scopus.com/pages/publications/0042871767

UR - https://www.scopus.com/pages/publications/0042871767#tab=citedBy

U2 - 10.1021/ma60054a014

DO - 10.1021/ma60054a014

M3 - Article

AN - SCOPUS:0042871767

SN - 0024-9297

VL - 9

SP - 950

EP - 955

JO - Macromolecules

JF - Macromolecules

IS - 6

ER -

Conformational Analysis of Poly(dihalophosphazenes)

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this