Converting a layer perovskite into a non-defective higher-order homologue: Topochemical synthesis of Eu2CaTi2O7

R. E. Schaak; E. N. Guidry; T. E. Mallouk

doi:10.1039/b009230b

Converting a layer perovskite into a non-defective higher-order homologue: Topochemical synthesis of Eu₂CaTi₂O₇

R. E. Schaak, E. N. Guidry, T. E. Mallouk

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Abstract

Topochemical reduction of CaEu₂Ti₂O₈, a new n = 1 mixed Ruddlesden-Popper/Dion-Jacobson phase prepared by divalent ion-exchange of NaEuTiO₄, yields the non-defective n = 2 Ruddlesden-Popper phase Eu₂CaTi₂O₇.

Original language	English (US)
Pages (from-to)	853-854
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/b009230b
State	Published - May 7 2001

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b009230b

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title = "Converting a layer perovskite into a non-defective higher-order homologue: Topochemical synthesis of Eu2CaTi2O7",

abstract = "Topochemical reduction of CaEu2Ti2O8, a new n = 1 mixed Ruddlesden-Popper/Dion-Jacobson phase prepared by divalent ion-exchange of NaEuTiO4, yields the non-defective n = 2 Ruddlesden-Popper phase Eu2CaTi2O7.",

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AU - Mallouk, T. E.

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AB - Topochemical reduction of CaEu2Ti2O8, a new n = 1 mixed Ruddlesden-Popper/Dion-Jacobson phase prepared by divalent ion-exchange of NaEuTiO4, yields the non-defective n = 2 Ruddlesden-Popper phase Eu2CaTi2O7.

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Converting a layer perovskite into a non-defective higher-order homologue: Topochemical synthesis of Eu₂CaTi₂O₇

Abstract

All Science Journal Classification (ASJC) codes

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