Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

Surendra Thapa; Prakash Basnet; Santosh K. Gurung; Ramesh Giri

doi:10.1039/c5cc00116a

Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

Surendra Thapa, Prakash Basnet, Santosh K. Gurung, Ramesh Giri

Chemistry

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12 Scopus citations

Abstract

An unprecedented Cu^I-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp₂ZrAr₂ complex revealed that Cp₂Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway. This journal is

Original language	English (US)
Pages (from-to)	4009-4012
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	19
DOIs	https://doi.org/10.1039/c5cc00116a
State	Published - Mar 7 2015

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "An unprecedented CuI-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp2ZrAr2 complex revealed that Cp2Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway. This journal is",

author = "Surendra Thapa and Prakash Basnet and Gurung, {Santosh K.} and Ramesh Giri",

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T1 - Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

AU - Thapa, Surendra

AU - Basnet, Prakash

AU - Gurung, Santosh K.

AU - Giri, Ramesh

PY - 2015/3/7

Y1 - 2015/3/7

N2 - An unprecedented CuI-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp2ZrAr2 complex revealed that Cp2Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway. This journal is

AB - An unprecedented CuI-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp2ZrAr2 complex revealed that Cp2Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway. This journal is

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JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

Abstract

All Science Journal Classification (ASJC) codes

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