Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

Surendra Thapa; Prakash Basnet; Santosh K. Gurung; Ramesh Giri

doi:10.1039/c5cc00116a

Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

Surendra Thapa
, Prakash Basnet
, Santosh K. Gurung
, Ramesh Giri

Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

An unprecedented Cu^I-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp₂ZrAr₂ complex revealed that Cp₂Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway.

Original language	English (US)
Pages (from-to)	4009-4012
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	19
DOIs	https://doi.org/10.1039/c5cc00116a
State	Published - Mar 7 2015

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides",

abstract = "An unprecedented CuI-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp2ZrAr2 complex revealed that Cp2Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway.",

author = "Surendra Thapa and Prakash Basnet and Gurung, \{Santosh K.\} and Ramesh Giri",

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T1 - Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

AU - Thapa, Surendra

AU - Basnet, Prakash

AU - Gurung, Santosh K.

AU - Giri, Ramesh

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/3/7

Y1 - 2015/3/7

N2 - An unprecedented CuI-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp2ZrAr2 complex revealed that Cp2Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway.

AB - An unprecedented CuI-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp2ZrAr2 complex revealed that Cp2Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway.

UR - https://www.scopus.com/pages/publications/84923355809

UR - https://www.scopus.com/pages/publications/84923355809#tab=citedBy

U2 - 10.1039/c5cc00116a

DO - 10.1039/c5cc00116a

M3 - Article

AN - SCOPUS:84923355809

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SP - 4009

EP - 4012

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

Abstract

All Science Journal Classification (ASJC) codes

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