Copper(I) Phenoxide complexes in the etherification of aryl halides

Jesse W. Tye; Zhiqiang Weng; Ramesh Giri; John F. Hartwig

doi:10.1002/anie.200902245

Copper(I) Phenoxide complexes in the etherification of aryl halides

Jesse W. Tye, Zhiqiang Weng, Ramesh Giri, John F. Hartwig

Chemistry

Research output: Contribution to journal › Article › peer-review

133 Scopus citations

Abstract

"Chemical Equation Presented" No copping out! Copper(I) phenoxide complexes containing chelating ligands (see picture), proposed intermediates in copper-catalyzed etherification of aryl halides, have been synthesized and fully characterized. The kinetic and chemical competence of the isolated complexes are demonstrated for the synthesis of aryl phenyl ethers, and experiments provide evidence against mechanistic pathways involving the formation of either free or caged radicals.

Original language	English (US)
Pages (from-to)	2185-2189
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	12
DOIs	https://doi.org/10.1002/anie.200902245
State	Published - Mar 15 2010

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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AU - Hartwig, John F.

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Y1 - 2010/3/15

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Copper(I) Phenoxide complexes in the etherification of aryl halides

Abstract

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