Correlation between Phase-Separated Domain Sizes of Active Layer and Photovoltaic Performances in All-Polymer Solar Cells

Changyeon Lee, Yuxiang Li, Wonho Lee, Youngmin Lee, Joonhyeong Choi, Taesu Kim, Cheng Wang, Enrique D. Gomez, Han Young Woo, Bumjoon J. Kim

Research output: Contribution to journalArticlepeer-review

90 Scopus citations


The control of the bulk-heterojunction (BHJ) morphology in polymer/polymer blends remains a critical hurdle for optimizing all-polymer solar cells (all-PSCs). The relationship between donor/acceptor phase separation, domain size, and the resulting photovoltaic characteristics of PDFQx3T and P(NDI2OD-T2)-based all-PSCs was investigated. We varied the film-processing solvents (chloroform, chlorobenzene, o-dichlorobenzene, and p-xylene), thereby manipulating the phase separation of all-polymer blends with the domain size in the range of 30-300 nm. The different volatility and solubility of the solvents strongly influenced the aggregation of the polymers and the BHJ morphology of polymer blends. Domain sizes of all-polymer blends were closely correlated with the short-circuit current density (JSC) of the devices, while the open-circuit voltage (0.80 V) and fill factor (0.60) were unaffected. All-PSCs with the smallest domain size of ∼30 nm in the active layer (using chloroform), which is commensurate with the domain size of highly efficient polymer/fullerene solar cells, had the highest JSC and power conversion efficiency of 5.11% due to large interfacial areas and efficient exciton separation. Our results suggest that the BHJ morphology was not fully optimized for most of the previous high-performance all-PSC systems, and their photovoltaic performance can be further improved by fine-engineering the film morphology, i.e., domain size, domain purity, and polymer packing structure.

Original languageEnglish (US)
Pages (from-to)5051-5058
Number of pages8
Issue number14
StatePublished - Jul 26 2016

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry


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