Cu(i)-catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes with thiols for the construction of alkynyl sulfides

Yong Yang; Weibing Dong; Yisong Guo; Robert M. Rioux

doi:10.1039/c3gc41330f

Cu(i)-catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes with thiols for the construction of alkynyl sulfides

Yong Yang, Weibing Dong, Yisong Guo, Robert M. Rioux

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Highly active and selective aerobic cross-dehydrogenative coupling of terminal alkynes with thiols to construct alkynyl sulfides catalyzed by Cu(i) using molecular oxygen as the oxidant has been demonstrated under mild reaction conditions. The process is applicable to a wide range of alkynes and various thiols and is compatible with a variety of functional groups on both alkyne and thiol coupling partners.

Original language	English (US)
Pages (from-to)	3170-3175
Number of pages	6
Journal	Green Chemistry
Volume	15
Issue number	11
DOIs	https://doi.org/10.1039/c3gc41330f
State	Published - 2013

All Science Journal Classification (ASJC) codes

Environmental Chemistry
Pollution

Access to Document

10.1039/c3gc41330f

Cite this

@article{7326c5f1894a4ad88a5bc0d1d8bf4432,

title = "Cu(i)-catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes with thiols for the construction of alkynyl sulfides",

abstract = "Highly active and selective aerobic cross-dehydrogenative coupling of terminal alkynes with thiols to construct alkynyl sulfides catalyzed by Cu(i) using molecular oxygen as the oxidant has been demonstrated under mild reaction conditions. The process is applicable to a wide range of alkynes and various thiols and is compatible with a variety of functional groups on both alkyne and thiol coupling partners.",

author = "Yong Yang and Weibing Dong and Yisong Guo and Rioux, {Robert M.}",

year = "2013",

doi = "10.1039/c3gc41330f",

language = "English (US)",

volume = "15",

pages = "3170--3175",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Cu(i)-catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes with thiols for the construction of alkynyl sulfides

AU - Yang, Yong

AU - Dong, Weibing

AU - Guo, Yisong

AU - Rioux, Robert M.

PY - 2013

Y1 - 2013

N2 - Highly active and selective aerobic cross-dehydrogenative coupling of terminal alkynes with thiols to construct alkynyl sulfides catalyzed by Cu(i) using molecular oxygen as the oxidant has been demonstrated under mild reaction conditions. The process is applicable to a wide range of alkynes and various thiols and is compatible with a variety of functional groups on both alkyne and thiol coupling partners.

AB - Highly active and selective aerobic cross-dehydrogenative coupling of terminal alkynes with thiols to construct alkynyl sulfides catalyzed by Cu(i) using molecular oxygen as the oxidant has been demonstrated under mild reaction conditions. The process is applicable to a wide range of alkynes and various thiols and is compatible with a variety of functional groups on both alkyne and thiol coupling partners.

UR - http://www.scopus.com/inward/record.url?scp=84886390634&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84886390634&partnerID=8YFLogxK

U2 - 10.1039/c3gc41330f

DO - 10.1039/c3gc41330f

M3 - Article

AN - SCOPUS:84886390634

SN - 1463-9262

VL - 15

SP - 3170

EP - 3175

JO - Green Chemistry

JF - Green Chemistry

IS - 11

ER -

Cu(i)-catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes with thiols for the construction of alkynyl sulfides

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this