Abstract
Pd(OAc)2-mediated dehydrogenation of an alkyl group to a double bond or a η3-allylic complex via sp3 C-H bond activation and allylic oxidation is reported. A novel redox is proposed for this double oxidation under oxidant-free conditions. A catalytic protocol using benzoquinone as the stoichiometric oxidant has also been developed for the dehy- drogenation of cyclopentylcarboxamides.
Original language | English (US) |
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Pages (from-to) | 1667-1670 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 27 |
Issue number | 8 |
DOIs | |
State | Published - Apr 28 2008 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry